| Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets | |
| S. Y. Wu; H. N. Dong | |
| 2005 | |
| Source Publication | Journal of Alloys and Compounds
 |
| ISSN | 0925-8388 |
| Volume | 393Issue:1-2Pages:46-50 |
| Abstract | The EPR g factors g(x), g(y) and g(z) and the local structures for the orthorhombic Nd3+ centers in YAG, YGG and LuGG garnets are studied by using the perturbation formulas of the g factors for a 43 ion in orthorhombic symmetry. In these formulas, the contributions to the g factors arising from the second-order perturbation terms and the admixture of various energy levels are considered. Based on the analyses of the g factors, we find that the polar angles theta'(j) of the impurity-ligand bonds related to the Z-axis of the crystals in these Nd3+ centers are smaller than the host angles theta(j) in pure crystals, whereas the azimuthal angles phi'(j) related to the X-axis in the impurity centers are larger than the corresponding phi(j) in the hosts. The calculated g factors, particularly their anisotropies Delta g [= g(z) - (g(x) + g(y))/2] and delta g (= g(x) - g(y)) for Nd3+ in the gamets based on the above local angles show reasonable agreement with the observed values. (c) 2004 Elsevier B.V. All rights reserved. |
| description.department | univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. chongqing univ posts & telecommun, coll elect engn, chongqing 400065, peoples r china.;wu, sy (reprint author), univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china;wushaoyi@netease.com |
| Keyword | Electron Paramagnetic Resonance (Epr) Defect Structure Crystal-field And Spin Hamiltonians Nd3++ Garnets Crystal-field Substituted Garnets Superposition-model Magnetic-properties Neodymium Laser Parameters Calcium Cerium Ion |
| URL | 查看原文 |
| WOS ID | WOS:000228716700010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/35123 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | S. Y. Wu,H. N. Dong. Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets[J]. Journal of Alloys and Compounds,2005,393(1-2):46-50. |
| APA | S. Y. Wu,&H. N. Dong.(2005).Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets.Journal of Alloys and Compounds,393(1-2),46-50. |
| MLA | S. Y. Wu,et al."Theoretical investigations of the g factors and the local structures for the orthorhombic Nd3+ centers in the garnets".Journal of Alloys and Compounds 393.1-2(2005):46-50. |
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