X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys

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	X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys
	J. Xu; X. G. Li; X. B. Liu; C. F. Dong; N. Deem; E. Barbero
	2005
发表期刊	Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science
ISSN	1073-5623
卷号	36A 期号:8 页码:2175-2190
摘要	In this article, passivated Pb-Sn and Pb-Sb alloys with different compositions were studied by X-ray photoelectron spectroscopy (XPS). The passive films were found to have a double-layer structure. Both Sri and Sb were found to play an important role during the growth of passive film, which resulted in different compositions of passive films. The Pb oxides, Pb sulfate, Sn/Sb oxides, and Pb-Sn/Sb complex oxides (PbOx-Sn1-xO2, PbSb2O6) were present in the passive films. Both Sri and Sb facilitated PbOx (1 < x < 2) formation, which was considered to be very helpful to optimize the conductivity of passive films. It was also shown that the positions of peak signals of alloying Sn/Sb, Pb, and O were almost fixed, even though the contents of alloying Sn/Sb oxides were quite different in different specimens.
部门归属	w virginia univ, dept mech & aerosp engn, morgantown, wv 26506 usa. beijing univ sci & technol, key lab corros & eros, ctr corros & protect, beijing 100083, peoples r china. state key lab corros & protect, shenyang 110016, peoples r china.;xu, j (reprint author), w virginia univ, dept mech & aerosp engn, morgantown, wv 26506 usa;ixu3@mix.uwv.edu
关键词	Lead-acid-batteries Corrosion Layers Tin Plate
URL	查看原文
WOS记录号	WOS:000230798400019
引用统计	被引频次：6[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/35159
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. Xu,X. G. Li,X. B. Liu,et al. X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys[J]. Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,2005,36A(8):2175-2190.
APA	J. Xu,X. G. Li,X. B. Liu,C. F. Dong,N. Deem,&E. Barbero.(2005).X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys.Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,36A(8),2175-2190.
MLA	J. Xu,et al."X-ray photoelectron spectroscopy study of passive layers formed on Pb-Sn and Pb-Sb alloys".Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science 36A.8(2005):2175-2190.