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Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte
M. J. Yang; W. L. Li; G. G. Wang; J. Q. Zhang
2005
发表期刊Solid State Ionics
ISSN0167-2738
卷号176期号:37-38页码:2829-2834
摘要A new type of composite gel polymer electrolyte(CGPE) with a blend of polyethylene glycol 200 maleate, methyl methacrylate(MMA) and poly(methyl methacrylate)(PMMA) coated and polymerized on the microporous polyolefin membrane was prepared by means of ultra-violet crosslinking and then soaked in a lithium salt solution. The chemical construction, morphology, ionic conductivity of composite gel polymer electrolytes, and their interfacial stability between lithium metal electrode were characterized by using infrared spectroscopy, H-1 NMR measurement, scanning electron microscopy, alternating current impedance and linear sweep voltammetry, respectively. The ionic conductivity of the CGPE reaches 10(-3) S/cm at room temperature and its electrochemical stability window is 4.7 V, which makes it a potential candidate for application as polymer electrolyte in devices. (c) 2005 Elsevier B.V. All rights reserved.
部门归属zhejiang univ, dept polymer sci & engn, hangzhou 310027, peoples r china. zhejiang univ, dept chem, hangzhou 310027, peoples r china. china state key lab corros & protect, shenyang 110015, peoples r china.;yang, mj (reprint author), zhejiang univ, dept polymer sci & engn, hangzhou 310027, peoples r china;yangmj@cmsce.zju.edu.cn
关键词Membrane Supporting Composite Gel Polymer Electrolyte Polyethylene Glycol 200 Maleate Uv Cross Linking Ionic Conductivity Ionic-conductivity
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35168
专题中国科学院金属研究所
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M. J. Yang,W. L. Li,G. G. Wang,et al. Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte[J]. Solid State Ionics,2005,176(37-38):2829-2834.
APA M. J. Yang,W. L. Li,G. G. Wang,&J. Q. Zhang.(2005).Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte.Solid State Ionics,176(37-38),2829-2834.
MLA M. J. Yang,et al."Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte".Solid State Ionics 176.37-38(2005):2829-2834.
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