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Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere
J. B. Zhang; J. Wang; Y. H. Wang
2005
发表期刊Electrochemistry Communications
ISSN1388-2481
卷号7期号:4页码:443-448
摘要The formation of micro-droplets, 1-10 mu m in diameter, were observed around the edge of main-droplet formed by the deliquescence of salt particles deposited on metals in atmosphere. The characteristics of the formation of micro-droplets were studied in a humidity-controlled chamber. The results showed that oxygen and relative humidity were the key variables for the formation of micro-droplets. Meanwhile, micro-droplets could only appear on the electropositive areas of metal surface based on the potential distributions with the scanning Kelvin probe. The electrochemical polarization results proved that the current established by the potential difference between the central and peripheral area of main-droplet was the true driving force for the formation of micro-droplets. (c) 2005 Elsevier B.V. All rights reserved.
部门归属chinese acad sci, inst oceanol, dept corros, qingdao 266071, peoples r china. chinese acad sci, grad sch, beijing 100039, peoples r china. ocean univ qingdao, qingdao 266003, peoples r china. state key lab corros & prot met, shenyang 110015, peoples r china.;zhang, jb (reprint author), chinese acad sci, inst oceanol, dept corros, 7 nanhai rd, qingdao 266071, peoples r china;zhangjibiao@ms.qdio.ac.cn
关键词Micro-droplets Formation Potential Distribution Electrochemical Polarization Atmospheric Corrosion Corrosion Water Spectroscopy Chloride Zinc Nucleation Interface Electrode Surfaces Growth
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35214
专题中国科学院金属研究所
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GB/T 7714
J. B. Zhang,J. Wang,Y. H. Wang. Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere[J]. Electrochemistry Communications,2005,7(4):443-448.
APA J. B. Zhang,J. Wang,&Y. H. Wang.(2005).Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere.Electrochemistry Communications,7(4),443-448.
MLA J. B. Zhang,et al."Electrochemical investigations of micro-droplets formed on metals during the deliquescence of salt particles in atmosphere".Electrochemistry Communications 7.4(2005):443-448.
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