Study of the zinc electroplating process using electrochemical noise technique

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	Study of the zinc electroplating process using electrochemical noise technique
	Z. Zhang; W. H. Leng; Q. Y. Cai; F. H. Cao; J. Q. Zhang
	2005
发表期刊	Journal of Electroanalytical Chemistry
ISSN	1572-6657
卷号	578 期号:2 页码:357-367
摘要	The zinc electroplating process was investigated by means of electrochemical noise (EN), cyclic voltammetry and steady-state polarization methods in conjunction with the scanning electron microscopy (SEM) technique. It was found that the EN generated during the electroplating of dentritic or large conglomerate zinc deposit has large potential oscillation amplitude and positive potential drift while the compact zinc deposit possesses small noise amplitude and little potential drift. Meanwhile, the electrocrystallization EN time-domain records were analyzed using wavelet transform technique, the results shown that, with the change of the rate determining step of zinc electroplating process from diffusion-control through mixed-control to activation-control, the maximum relative energy of the EDP (relative energy distribution plot) obtained from wavelet analysis shifted from the region with larger scales to those with smaller scales, and the corresponding deposit structure changed from dentritic to compact, i.e., the EDP can be used as "fingerprints" of EN to characterize the electroplating process and the deposit structure. The results also shown that electrochemical noise technique can give more information about the deposit structure than other normal electrochemical measurements, such as linear potential sweep method and cyclic voltammetry technique. (c) 2005 Elsevier B.V. All rights reserved.
部门归属	zhejiang univ, inst electrochem, dept chem, hangzhou 310027, peoples r china. state key lab corros & protect, shenyang 110015, peoples r china.;zhang, z (reprint author), zhejiang univ, inst electrochem, dept chem, yu quan campus, hangzhou 310027, peoples r china;eaglezzy@zjuem.zju.edu.cn
关键词	Zinc Electroplating Electrochemical Noise Electrodeposit Structure Glassy-carbon Layered Nanostructures Copper/cuprous Oxide Wavelets Transform Electrodeposition Nucleation Electrocrystallization Crystallization Behavior Silver
URL	查看原文
WOS记录号	WOS:000228788300019
引用统计	被引频次：44[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/35247
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Z. Zhang,W. H. Leng,Q. Y. Cai,et al. Study of the zinc electroplating process using electrochemical noise technique[J]. Journal of Electroanalytical Chemistry,2005,578(2):357-367.
APA	Z. Zhang,W. H. Leng,Q. Y. Cai,F. H. Cao,&J. Q. Zhang.(2005).Study of the zinc electroplating process using electrochemical noise technique.Journal of Electroanalytical Chemistry,578(2),357-367.
MLA	Z. Zhang,et al."Study of the zinc electroplating process using electrochemical noise technique".Journal of Electroanalytical Chemistry 578.2(2005):357-367.