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Theoretical studies of the optical spectra and EPR parameters of CaWO4 : Sm3+ crystal
H. N. Dong; H. Tang; X. B. Luo; S. Y. Wu
2004
发表期刊Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
ISSN0932-0784
卷号59期号:3页码:113-115
摘要The optical spectra and EPR parameters (g factors g(\\), g(perpendicular to) and hyperfine structure parameters A(\\), A(perpendicular to) of Sm-147 and Sm-149) of Sm3+ in CaWO4 crystal are calculated from the second-order perturbation formulas of EPR parameters for a 4f(5) ion in tetragonal symmetry. In these formulas, the J-mixing among the H-6(J)(J = 5/2, 7/2 and 9/2) states via crystal-field interactions, the mixtures among the states with the same J value via spin-orbit coupling interaction and the interactions between the lowest Kramers doublet Gamma(gamma) and the same irreducible representations in the other 11 Kramers doublets Gamma(x) via the crystal-field and orbital angular momentum (or hyperfine structure) are considered. The theoretical results agree reasonably with the observed values.
部门归属chongqing univ posts & telecommun, inst appl phys, chongqing 400065, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. chongqing univ posts & telecommun, coll elect engn, chongqing 400065, peoples r china. univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china.;dong, hn (reprint author), chongqing univ posts & telecommun, inst appl phys, chongqing 400065, peoples r china;donghn@cqupt.edu.cn
关键词Epr : Crystal Field Theory Sm3++ Cawo4 Calcium Tungstate Up-conversion Samarium
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WOS记录号WOS:000221081900002
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35342
专题中国科学院金属研究所
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H. N. Dong,H. Tang,X. B. Luo,et al. Theoretical studies of the optical spectra and EPR parameters of CaWO4 : Sm3+ crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2004,59(3):113-115.
APA H. N. Dong,H. Tang,X. B. Luo,&S. Y. Wu.(2004).Theoretical studies of the optical spectra and EPR parameters of CaWO4 : Sm3+ crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,59(3),113-115.
MLA H. N. Dong,et al."Theoretical studies of the optical spectra and EPR parameters of CaWO4 : Sm3+ crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 59.3(2004):113-115.
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