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Preparation and hydrogenation characteristics of Mg-30 wt.% Ti37.5V25Cr37.5 composite
Y. Q. Hu; C. Yan; H. F. Zhang; L. Ye; Z. Q. Hu
2004
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号375期号:1-2页码:265-269
摘要A Mg-30 wt.% Ti37.5V25Cr37.5 hydrogen storage composite was successfully synthesized by reactive mechanical milling of a mixture of magnesium and Ti37.5V25Cr37.5 powder in a hydrogen atmosphere. The structural evolution during milling and after hydrogen absorption/desorption cycling was analyzed using XRD. The absorption/desorption rates and storage capacity at different temperatures were evaluated. By analyzing the variation of the Avrami exponent, the hydrogenation mechanisms during milling process were also estimated. A large hydrogen storage capacity and excellent absorption/desorption kinetics were achieved in this composite. (C) 2003 Published by Elsevier B.V.
部门归属chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. univ sydney, sch aerosp mech & mechatr engn, ctr adv mat technol, sydney, nsw 2006, australia.;hu, yq (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china;huyeqi@imr.ac.cn
关键词Mg-based Alloys Hydrogen Storage Materials Reactive Ball Milling Catalyst Absorption Kinetics Hydrogen Absorbing Materials Metal Hybrides Mechanochernical Processing Gas-solid Reactions Protium Absorption-desorption Storage Properties Hydriding/dehydriding Properties Nanocrystalline Mg Alloys Sorption Kinetics Microstructure System
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WOS记录号WOS:000222543800045
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被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35375
专题中国科学院金属研究所
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Y. Q. Hu,C. Yan,H. F. Zhang,et al. Preparation and hydrogenation characteristics of Mg-30 wt.% Ti37.5V25Cr37.5 composite[J]. Journal of Alloys and Compounds,2004,375(1-2):265-269.
APA Y. Q. Hu,C. Yan,H. F. Zhang,L. Ye,&Z. Q. Hu.(2004).Preparation and hydrogenation characteristics of Mg-30 wt.% Ti37.5V25Cr37.5 composite.Journal of Alloys and Compounds,375(1-2),265-269.
MLA Y. Q. Hu,et al."Preparation and hydrogenation characteristics of Mg-30 wt.% Ti37.5V25Cr37.5 composite".Journal of Alloys and Compounds 375.1-2(2004):265-269.
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