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Preparation, thermal stability and magnetic properties of Fe-Co-Ni-Zr-Mo-B bulk metallic glass
D. Y. Liu; W. S. Sun; H. F. Zhang; Z. Q. Hu
2004
发表期刊Intermetallics
ISSN0966-9795
卷号12期号:10-11页码:1149-1152
摘要A new bulk metallic glass Fe56Co7Ni2Zr10Mo5B20 rod with a diameter of 1.5 mm was prepared by copper mould casting from industrial raw materials. The amorphous state and crystallization behaviour were investigated by X-ray diffraction. The thermal stability, such as the glass transition temperature (T-g), the onset temperature of crystallization (T-x), supercooled liquid region (DeltaT(x)) between T-g and T-x, and reduced glass temperature T-rg(T-g/T-m), the ratio of the glass transition temperature (T-g) and the onset temperature of melting (T-m) were measured by differential scanning calorimetry to be 868, 937, 69 K and 0.596, respectively. The crystallization products are determined to be alpha-Fe, ZrFe2, Fe3B, MoB2, and Mo2FeB2 and an unknown phase, as determined by X-ray analysis of the sample annealed for 1.5 ks at 973 K. This bulk metallic alloy exhibits ferromagnetic properties with saturation magnetization (M-s) of 41.6 emu/g, and low coercivity for the as-cast rod of 1.5 mm diameter. (C) 2004 Elsevier Ltd. All rights reserved.
部门归属chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110006, peoples r china.;zhang, hf (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110006, peoples r china;hfzhang@imr.ac.cn
关键词Glasses Metallic Magnetic Properties Thermal Stability High Saturation Magnetization Ferromagnetic Glasses Supercooled Liquid Amorphous-alloys Forming Ability 1.5 t System Strength
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WOS记录号WOS:000224566700020
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被引频次:27[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/35449
专题中国科学院金属研究所
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D. Y. Liu,W. S. Sun,H. F. Zhang,et al. Preparation, thermal stability and magnetic properties of Fe-Co-Ni-Zr-Mo-B bulk metallic glass[J]. Intermetallics,2004,12(10-11):1149-1152.
APA D. Y. Liu,W. S. Sun,H. F. Zhang,&Z. Q. Hu.(2004).Preparation, thermal stability and magnetic properties of Fe-Co-Ni-Zr-Mo-B bulk metallic glass.Intermetallics,12(10-11),1149-1152.
MLA D. Y. Liu,et al."Preparation, thermal stability and magnetic properties of Fe-Co-Ni-Zr-Mo-B bulk metallic glass".Intermetallics 12.10-11(2004):1149-1152.
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