Influence of size of NiO on the electrochemical properties for SOFC anodes | |
J. X. Wang; Y. Ji; D. P. Xu; T. M. He; W. R. Wang; X. F. Zhou; W. H. Su | |
2004 | |
发表期刊 | Chemical Journal of Chinese Universities-Chinese
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ISSN | 0251-0790 |
卷号 | 25期号:3页码:501-503 |
摘要 | Nanometric NiO with a high specific surface area was synthesized by sol-gel method. NiO-YSZ anode materials were prepared by solid state reaction and their impedance spctra were measured. The analysis results show that NiO-YSZ anode materials with nanometric oxide NiO have a smaller polarization resistance R-p, higher conductivity than those with original powder NiO. The single cell with the anode of nanometric NiO-YSZ in 55% mass fraction has a higher power density and higher current density than that of the cell with the anode of original power NiO-YSZ in the same mass fraction. These demonstrate that the optimization of the anode can be obtained by increasing the three-phase boundary(TPB) line among Nickel, YSZ and Hydrogen, which can be achieved by decreasing the size of the NiO. |
部门归属 | jilin univ, ctr rare earth solid states phys, dept condensed matter phys, changchun 130023, peoples r china. harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china. environm management inst china, qinhuangdao 066004, peoples r china.;su, wh (reprint author), jilin univ, ctr rare earth solid states phys, dept condensed matter phys, changchun 130023, peoples r china |
关键词 | Sol-gel Method Three-phase Boundaries Sofc Anode Electrodes Cermet |
URL | 查看原文 |
WOS记录号 | WOS:000220526000027 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35583 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. X. Wang,Y. Ji,D. P. Xu,et al. Influence of size of NiO on the electrochemical properties for SOFC anodes[J]. Chemical Journal of Chinese Universities-Chinese,2004,25(3):501-503. |
APA | J. X. Wang.,Y. Ji.,D. P. Xu.,T. M. He.,W. R. Wang.,...&W. H. Su.(2004).Influence of size of NiO on the electrochemical properties for SOFC anodes.Chemical Journal of Chinese Universities-Chinese,25(3),501-503. |
MLA | J. X. Wang,et al."Influence of size of NiO on the electrochemical properties for SOFC anodes".Chemical Journal of Chinese Universities-Chinese 25.3(2004):501-503. |
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