Theoretical studies of the spin-Hamiltonian parameters for Er3+ in CaWO4 and SrWO4 | |
S. Y. Wu; H. N. Dong; W. Z. Yan; X. Y. Gao | |
2004 | |
发表期刊 | Physica Status Solidi B-Basic Research
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ISSN | 0370-1972 |
卷号 | 241期号:5页码:1073-1077 |
摘要 | The spin-Hamiltonian parameters g factors g(parallel to), gperpendicular to and hyperfine structure parameters A(parallel to) and A(perpendicular to) for Er3+ (Er-167) in CaWO4 and SrWO4 are theoretically studied by using the perturbation formulas of the spin-Hamiltonian parameters for a 4f(11) ion in tetragonal symmetry. In these formulas, the contributions to the spin-Hamiltonian parameters arising from the second-order perturbation terms and the admixture of various states are considered. The crystal-field parameters for the tetragonally distorted tetrahedra are calculated from the superposition model and the local structural data of the impurity Er 3, ions at the host Ca2+ and Sr2+ sites. The theoretical parameters are in agreement with the experimental values. The validity of the results is discussed. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
部门归属 | univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. chongqing univ posts & telecommun, coll elect engn, chongqing 400065, peoples r china.;wu, sy (reprint author), univ elect sci & technol china, dept appl phys, chengdu 610054, peoples r china;wushaoyi@netease.com |
关键词 | Electron Paramagnetic Resonance Superposition-model Optical-properties Single-crystals Scheelite Field Ion Tungstate Lasers State |
URL | 查看原文 |
WOS记录号 | WOS:000220943400014 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35632 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | S. Y. Wu,H. N. Dong,W. Z. Yan,et al. Theoretical studies of the spin-Hamiltonian parameters for Er3+ in CaWO4 and SrWO4[J]. Physica Status Solidi B-Basic Research,2004,241(5):1073-1077. |
APA | S. Y. Wu,H. N. Dong,W. Z. Yan,&X. Y. Gao.(2004).Theoretical studies of the spin-Hamiltonian parameters for Er3+ in CaWO4 and SrWO4.Physica Status Solidi B-Basic Research,241(5),1073-1077. |
MLA | S. Y. Wu,et al."Theoretical studies of the spin-Hamiltonian parameters for Er3+ in CaWO4 and SrWO4".Physica Status Solidi B-Basic Research 241.5(2004):1073-1077. |
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