| Electrochemical impedance spectra for the corrosion of two-phase Cu-15Al alloy in eutectic (Li, K)(2)CO3 at 650 degrees C in air | |
| C. L. Zeng; P. Y. Guo; W. T. Wu | |
| 2004 | |
| Source Publication | Electrochimica Acta
 |
| ISSN | 0013-4686 |
| Volume | 49Issue:9-10Pages:1445-1450 |
| Abstract | The electrochemical impedance technique was employed to study the corrosion of two-phase Cu-15Al alloy in molten (0.62Li, 0.38K)(2)CO3 at 650degreesC in air. The results indicate that the corrosion of the alloy goes through two stages. In initial stage, the corrosion of the alloy shows typical features of a diffusion-controlled reaction. With extended immersion, the Nyquist plots are composed of a large capacitive loop at low frequency, a line at intermediate frequency and a small semicircle at high frequency, which is related to the formation of a protective Al2O3 scale. Two impedance models were proposed to describe the corrosion of the alloy. (C) 2003 Elsevier Ltd. All rights reserved. |
| description.department | chinese acad sci, inst met res, state key lab corros & protect, shenyang 110015, peoples r china.;zeng, cl (reprint author), chinese acad sci, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110015, peoples r china, peoples r china;clzeng@imr.ac.cn |
| Keyword | Cu-15al Alloy Molten (0.62li 0.38k)(2)Co3 Electrochemical Impedance Spectrum Corrosion Molten Carbonate Fuel Cell Carbonate Fuel-cells Molten-carbonate Hot-corrosion Oxidation Electrode Mechanism Cathodes Behavior Steels Nickel |
| URL | 查看原文 |
| WOS ID | WOS:000189226300010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/35701 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | C. L. Zeng,P. Y. Guo,W. T. Wu. Electrochemical impedance spectra for the corrosion of two-phase Cu-15Al alloy in eutectic (Li, K)(2)CO3 at 650 degrees C in air[J]. Electrochimica Acta,2004,49(9-10):1445-1450. |
| APA | C. L. Zeng,P. Y. Guo,&W. T. Wu.(2004).Electrochemical impedance spectra for the corrosion of two-phase Cu-15Al alloy in eutectic (Li, K)(2)CO3 at 650 degrees C in air.Electrochimica Acta,49(9-10),1445-1450. |
| MLA | C. L. Zeng,et al."Electrochemical impedance spectra for the corrosion of two-phase Cu-15Al alloy in eutectic (Li, K)(2)CO3 at 650 degrees C in air".Electrochimica Acta 49.9-10(2004):1445-1450. |
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