EXAFS study of mechanical-milling-induced solid-state amorphization of Se | |
Y. H. Zhao; K. Lu; T. Liu | |
2004 | |
Source Publication | Journal of Non-Crystalline Solids
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ISSN | 0022-3093 |
Volume | 333Issue:3Pages:246-251 |
Abstract | Complete solid-state amorphization has been realized in elemental selenium by means of mechanical milling of crystalline Se powder. Extended X-ray-absorption fine-structure measurements (EXAFS) indicated that the amorphization process of crystalline Se was accompanied with a decrease of the nearest neighboring coordination number and the bond length, and the increase of the Debye-Waller factor. Combined with the previous study, we conclude that the mechanical milling results in the strengthening of intra-chain and weakening of inter-chain interactions of Se during amorphization. Compared to the structure of the as-quenched amorphous Se, the first nearest neighbor coordination number of the as-milled amorphous Se becomes smaller, while the Debye-Waller factor is larger, which is caused by the milling process. (C) 2004 Published by Elsevier B.V. |
description.department | chinese acad sci, met res inst, shenyang natl lab mat sci, shenyang 110016, peoples r china. chinese acad sci, inst high energy phys, synchrotron radiat lab, beijing 100039, peoples r china.;zhao, yh (reprint author), los alamos natl lab, mst stc,g755, los alamos, nm 87545 usa;zhao@lanl.gov |
Keyword | Absorption Fine-structure Different Grain Sizes Amorphous Selenium Silicon Attrition Crystal Alloys Zr |
URL | 查看原文 |
WOS ID | WOS:000188784600003 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/35745 |
Collection | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | Y. H. Zhao,K. Lu,T. Liu. EXAFS study of mechanical-milling-induced solid-state amorphization of Se[J]. Journal of Non-Crystalline Solids,2004,333(3):246-251. |
APA | Y. H. Zhao,K. Lu,&T. Liu.(2004).EXAFS study of mechanical-milling-induced solid-state amorphization of Se.Journal of Non-Crystalline Solids,333(3),246-251. |
MLA | Y. H. Zhao,et al."EXAFS study of mechanical-milling-induced solid-state amorphization of Se".Journal of Non-Crystalline Solids 333.3(2004):246-251. |
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