EPR parameters and superposition model analysis for trigonal Dy3+-O2- center in CaF2 crystal | |
W. C. Zheng; H. N. Dong; S. Y. Wu; T. Sheng | |
2004 | |
发表期刊 | Physica B-Condensed Matter
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ISSN | 0921-4526 |
卷号 | 344期号:1-4页码:103-107 |
摘要 | On the basis of the defect model of trigonal Dy3+-O2- center in CaF2, the EPR parameters (g factors and hyperfine structure constants) for this trigonal center are calculated from the perturbation formulas. In the formulas, the contributions to EPR parameters due to the J-mixing among H-6(J) (J = 15/2, 13/2 and 11/2) states, the mixtures among the states with the same J-value and those between the lowest Kramers doublet Gamma(gamma) and other Kramers doublets Gamma(X) are included. In the calculation, the crystal field parameters are estimated from the superposition model. From the calculation, the EPR g factors g(\\), g(perpendicular to) are reasonably explained and the superposition model intrinsic parameters (A) over bar (2)(F-) and (A) over bar (2) (O2-) with R = 2.366 Angstrom are obtained. (C) 2003 Elsevier B.V. All rights reserved. |
部门归属 | sichuan univ, dept mat sci, chengdu 610064, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. sichuan normal univ, inst solid state phys, chengdu 610066, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwenchen@netease.com |
关键词 | Epr Parameters Crystal-field Theory Superposition Model Dy3++ Caf2 Electron-paramagnetic-resonance Field Parameters Single-crystals Ions |
URL | 查看原文 |
WOS记录号 | WOS:000189038200015 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35754 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,H. N. Dong,S. Y. Wu,et al. EPR parameters and superposition model analysis for trigonal Dy3+-O2- center in CaF2 crystal[J]. Physica B-Condensed Matter,2004,344(1-4):103-107. |
APA | W. C. Zheng,H. N. Dong,S. Y. Wu,&T. Sheng.(2004).EPR parameters and superposition model analysis for trigonal Dy3+-O2- center in CaF2 crystal.Physica B-Condensed Matter,344(1-4),103-107. |
MLA | W. C. Zheng,et al."EPR parameters and superposition model analysis for trigonal Dy3+-O2- center in CaF2 crystal".Physica B-Condensed Matter 344.1-4(2004):103-107. |
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