A Ni/YSZ composite containing Ce0.9Ca0.1O2-delta particles as an anode for SOFCs | |
X. Q. Huang; Z. G. Liu; Z. Lu; L. Pei; R. B. Zhu; Y. Q. Liu; J. P. Miao; Z. G. Zhang; W. H. Su | |
2003 | |
发表期刊 | Journal of Physics and Chemistry of Solids
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ISSN | 0022-3697 |
卷号 | 64期号:12页码:2379-2384 |
摘要 | A composite material (hereafter referred to as NYC) containing Ni, Y2O3-stabilized ZrO2 (YSZ) and Ce0.9Ca0.1O2-delta (CC10) particles was prepared and used as the anode of solid oxide fuel cells (SOFCs). The performance of NYC was better than that of conventional Ni/YSZ anodes in terms of anodic overpotential and interface impedance. The additional CC10 particles improved the anode properties. XRD results suggest that a solid solution of YSZ and CC10 was produced. From impedance measurements, it is concluded that the solid solution exhibits substantial electronic conduction. Ni/YSZ/15 wt% Ce0.9Ca0.1O2-delta anodes exhibited the best properties over the experimental temperature range. A SOFC with an anode of Ni/YSZ/15 wt% Ce0.9Ca0.1O2-delta provided the maximum power density and current density. Addition of CC10 with an average particle size of 0.3 mum was more advantageous than that with an average size of 3 mum. (C) 2003 Elsevier Ltd. All rights reserved. |
部门归属 | harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china. jilin univ, dept condensed matter phys, changchun 130023, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;huang, xq (reprint author), harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china |
关键词 | Ceramics Oxides Interfaces Electrochemical Properties Oxide Fuel-cells Lanthanum Gallate Electrolyte Gadolinia-doped Ceria Sdc Cermet Anode Nonlinear Susceptibility Solid-electrolyte Performance Deposition Films Ysz |
URL | 查看原文 |
WOS记录号 | WOS:000186575700010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35860 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | X. Q. Huang,Z. G. Liu,Z. Lu,et al. A Ni/YSZ composite containing Ce0.9Ca0.1O2-delta particles as an anode for SOFCs[J]. Journal of Physics and Chemistry of Solids,2003,64(12):2379-2384. |
APA | X. Q. Huang.,Z. G. Liu.,Z. Lu.,L. Pei.,R. B. Zhu.,...&W. H. Su.(2003).A Ni/YSZ composite containing Ce0.9Ca0.1O2-delta particles as an anode for SOFCs.Journal of Physics and Chemistry of Solids,64(12),2379-2384. |
MLA | X. Q. Huang,et al."A Ni/YSZ composite containing Ce0.9Ca0.1O2-delta particles as an anode for SOFCs".Journal of Physics and Chemistry of Solids 64.12(2003):2379-2384. |
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