Subsolidus phase relations of the constant copper oxide content (50 mol%) section in the PrO(11/6)-BaO-CaO-CuO system at 950 degrees C | |
G. B. Song; J. K. Liang; L. T. Yang; F. S. Liu; G. H. Rao | |
2003 | |
发表期刊 | Journal of Alloys and Compounds
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ISSN | 0925-8388 |
卷号 | 360期号:1-2页码:316-321 |
摘要 | Subsolidus phase relations of the constant copper oxide content (50 mol%) section in the PrO(11/6)-BaO-CaO-CuO system at 950 degreesC in air are investigated by means of X-ray diffraction analyses. The phase relations consist of I single-phase region, I two-phase region, 2 three-phase regions and 6 four-phase regions. Mutual substitutions among Pr, Ba and Ca in the Pr123 structure were studied in detail. The result indicates that Ba ions can be replaced exclusively by Pr ions, but not by Ca ions, whereas Ca ions can partially occupy the sites of Pr ions. The ionic radius plays a more important role than the chemical property for substitution among Pr, Ba and Ca ions in the Pr123 structure. (C) 2003 Elsevier B.V. All fights reserved. |
部门归属 | chinese acad sci, inst phys, beijing 100080, peoples r china. chinese acad sci, ctr condensed matter phys, beijing 100080, peoples r china. sw univ sci & technol, sch mat sci & engn, mianyang 621002, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;song, gb (reprint author), chinese acad sci, inst phys, pob 603, beijing 100080, peoples r china;gbsong@aphy.iphy.ac.cn |
关键词 | Subsolidus Phase Relation Pro(11/6)-bao-cao-cuo System The Constant Cuprite Oxide Content (50 Mol%) Section Substitution Cu-o System Crystal-structure Approximately 950-degrees-c Superconductivity Diagram Property Powder Air |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/36024 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. B. Song,J. K. Liang,L. T. Yang,et al. Subsolidus phase relations of the constant copper oxide content (50 mol%) section in the PrO(11/6)-BaO-CaO-CuO system at 950 degrees C[J]. Journal of Alloys and Compounds,2003,360(1-2):316-321. |
APA | G. B. Song,J. K. Liang,L. T. Yang,F. S. Liu,&G. H. Rao.(2003).Subsolidus phase relations of the constant copper oxide content (50 mol%) section in the PrO(11/6)-BaO-CaO-CuO system at 950 degrees C.Journal of Alloys and Compounds,360(1-2),316-321. |
MLA | G. B. Song,et al."Subsolidus phase relations of the constant copper oxide content (50 mol%) section in the PrO(11/6)-BaO-CaO-CuO system at 950 degrees C".Journal of Alloys and Compounds 360.1-2(2003):316-321. |
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