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Electrochemical behavior of organic and inorganic zinc-rich coatings in 3.5 % NaCl solution
D. M. Xie; J. M. Wang; J. M. Hu; J. Q. Zhang
2003
发表期刊Transactions of Nonferrous Metals Society of China
ISSN1003-6326
卷号13期号:2页码:421-425
摘要Performance comparisons between organic and inorganic zinc-rich paints (ZRPs) were carried out. Electrochemical impedance spectroscopy (EIS) Measurements were used to assess the corrosion prevention performance of the ZRP coatings. The results show that during the cathodic protection period the potentials of the epoxy systems are less negative than those of the silicate system. For the zinc-rich ethyl silicate paints, the initial values of the resistance through the binder and the charge transfer resistance associated with zinc dissolution are several orders of magnitude lower than those of the organic zinc paints, while the initial values of the capacitance due to the binder layer between Zn dust and the double layer capacitance for zinc dissolution are several orders of magnitude higher than those of the organic zinc paints. Furthermore, the deterioration with time of capability of the zinc particles in the paint to provide cathodic protection to the steel was interpreted.
部门归属zhejiang univ, dept chem, hangzhou 310027, peoples r china. chinese acad sci, inst met res, state key lab corros & protect met, shenyang 110016, peoples r china.
关键词Zinc-rich Paints Epoxy Ethyl Silicate Electrochemical Impedance Spectroscopy Cathodic Protection Cathodic Protection Impedance Spectroscopy Paints Mechanism Stage
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WOS记录号WOS:000182726000039
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/36092
专题中国科学院金属研究所
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D. M. Xie,J. M. Wang,J. M. Hu,et al. Electrochemical behavior of organic and inorganic zinc-rich coatings in 3.5 % NaCl solution[J]. Transactions of Nonferrous Metals Society of China,2003,13(2):421-425.
APA D. M. Xie,J. M. Wang,J. M. Hu,&J. Q. Zhang.(2003).Electrochemical behavior of organic and inorganic zinc-rich coatings in 3.5 % NaCl solution.Transactions of Nonferrous Metals Society of China,13(2),421-425.
MLA D. M. Xie,et al."Electrochemical behavior of organic and inorganic zinc-rich coatings in 3.5 % NaCl solution".Transactions of Nonferrous Metals Society of China 13.2(2003):421-425.
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