| Electrolyte and electrode materials of intermedium-temperature SOFC prepared by glycine-nitrate process |
| Y. Ji; J. Liu; T. M. He; L. G. Cong; W. H. Su
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| 2002
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发表期刊 | Chemical Journal of Chinese Universities-Chinese
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ISSN | 0251-0790
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卷号 | 23期号:7页码:1227-1230 |
摘要 | By using a new combustion synthesis method, the glycine-nitrate process, all the nano-size materials were prepared for a single solid-oxide fuel cell (SOFC), in which (CeO2)(x) (SmO1.5)(1-x)(x = 0. 9, 0. 85, 0. 8) were used as the electrolytes, La0.6Sr0.4Fe0.8Co0.2O3 with 50% samaria-doped ceria (SDC) was selected as the cathode material, and a SDC-NiO-Ni composite powder was used as the anode material. In this study, the performance of the SOFC was obtained up to 750 degreesC, the maximum power density of 0. 104 W/cm(2) and a short circuit current density of 500 mA/cm(2) of the cell was achieved at 750 degreesC by using (CeO2)(0.9)(SmO1.5)(0.1) electrolyte. The inferior SOFC performance of the (CeO2)(0.8)(SmO1.5)(0.2) electrolyte was due to the physical discontinuity at the clearly grain boundary and could effectively introduce barriers to ionic conduction in reducing atmosphere, while the (CeO2)(0.9)(SmO1.5)(0.1) electrolyte's boundary tends to be merged. |
部门归属 | jilin univ, state key lab inorgan synth & preparat chem, ctr rare earth solid state phys & solid state phy, changchun 130023, peoples r china. harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china.;ji, y (reprint author), jilin univ, state key lab inorgan synth & preparat chem, ctr rare earth solid state phys & solid state phy, changchun 130023, peoples r china
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关键词 | Glycine-nitrate Process
Intermedium-temperature Sofc
(Ceo2)(0.9)(Smo1.5)(0.1)
Cathode
Anode
Anode
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URL | 查看原文
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WOS记录号 | WOS:000176908400003
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引用统计 |
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文献类型 | 期刊论文
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条目标识符 | http://ir.imr.ac.cn/handle/321006/36297
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专题 | 中国科学院金属研究所
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推荐引用方式 GB/T 7714 |
Y. Ji,J. Liu,T. M. He,et al. Electrolyte and electrode materials of intermedium-temperature SOFC prepared by glycine-nitrate process[J]. Chemical Journal of Chinese Universities-Chinese,2002,23(7):1227-1230.
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APA |
Y. Ji,J. Liu,T. M. He,L. G. Cong,&W. H. Su.(2002).Electrolyte and electrode materials of intermedium-temperature SOFC prepared by glycine-nitrate process.Chemical Journal of Chinese Universities-Chinese,23(7),1227-1230.
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MLA |
Y. Ji,et al."Electrolyte and electrode materials of intermedium-temperature SOFC prepared by glycine-nitrate process".Chemical Journal of Chinese Universities-Chinese 23.7(2002):1227-1230.
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