Properties and application of double alkali earth doped Ce0.9Ca01-xSrxO1.90 | |
Z. Lu; X. Q. Huang; W. Liu; T. M. He; Z. G. Liu; J. Liu; W. H. Su | |
2002 | |
发表期刊 | Journal of Rare Earths
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ISSN | 1002-0721 |
卷号 | 20期号:1页码:47-50 |
摘要 | A series of solid solution material based on ceria, Ce0.9Ca0.1-xSrxO1.90(x = 0, 0.04, 0.05, 0.06), were synthesized by a solid reaction method. Ceria doped with two alkali earth elements has cubic fluorite structure. The ionic conductivity of these materials at high temperature was studied by impedance spectra, and an increasing effect of ionic conductivity was found. A maximum conductivity is achieved when the effective ionic radius is near to the critical radius (0.1106 nm). Some fuel cells were made using these materials as electrolyte. The output power and current of the SOFC with the electrolyte of double doped ceria are better than those of YSZ and single doped ceria, and the open-circuit-voltage of the double doped ceria is also higher than that of the single doped ones. |
部门归属 | jilin univ, dept phys, changchun 130023, peoples r china. harbin inst technol, ctr condensed matter sci & technol, harbin 150001, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china. |
关键词 | Rare Earths Ceria Alkali Earth Double Doped Ionic Conductivity Intermediate Temperature Electrolyte Oxide Fuel-cells Ionic-conductivity Solid Electrolytes Ceria Yttria |
URL | 查看原文 |
WOS记录号 | WOS:000174459300010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/36363 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Z. Lu,X. Q. Huang,W. Liu,et al. Properties and application of double alkali earth doped Ce0.9Ca01-xSrxO1.90[J]. Journal of Rare Earths,2002,20(1):47-50. |
APA | Z. Lu.,X. Q. Huang.,W. Liu.,T. M. He.,Z. G. Liu.,...&W. H. Su.(2002).Properties and application of double alkali earth doped Ce0.9Ca01-xSrxO1.90.Journal of Rare Earths,20(1),47-50. |
MLA | Z. Lu,et al."Properties and application of double alkali earth doped Ce0.9Ca01-xSrxO1.90".Journal of Rare Earths 20.1(2002):47-50. |
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