Intermediate phases in Ti3SiC2 synthesis from Ti/SiC/C mixtures studied by time-resolved neutron diffraction

IMR OpenIR

	Intermediate phases in Ti3SiC2 synthesis from Ti/SiC/C mixtures studied by time-resolved neutron diffraction
	E. D. Wu; E. H. Kisi; D. P. Riley; R. I. Smith
	2002
发表期刊	Journal of the American Ceramic Society
ISSN	0002-7820
卷号	85 期号:12 页码:3084-3086
摘要	The reactive sintering of 3Ti/SiC/C to form the layered ternary carbide Ti3SiC2 was studied in situ by time-resolved neutron powder diffraction. A number of intermediate processes occur during the synthesis beginning with the alpha-beta transition in Ti. Concurrent with the alpha-beta transition, two intermediate phases, TiCx and Ti5Si3Cx (x less than or equal to 1), form. These phases account for almost the entire sample in the range 1500-1600degreesC beyond which they react with each other and a small amount of free C to form the product phase Ti3SiC2.
部门归属	univ newcastle, dept mech engn, callaghan, nsw 2308, australia.;wu, ed (reprint author), chinese acad sci, met res inst, shenyang natl lab mat sci, shenyang 11016, peoples r china
关键词	Powder Diffraction
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/36452
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	E. D. Wu,E. H. Kisi,D. P. Riley,et al. Intermediate phases in Ti3SiC2 synthesis from Ti/SiC/C mixtures studied by time-resolved neutron diffraction[J]. Journal of the American Ceramic Society,2002,85(12):3084-3086.
APA	E. D. Wu,E. H. Kisi,D. P. Riley,&R. I. Smith.(2002).Intermediate phases in Ti3SiC2 synthesis from Ti/SiC/C mixtures studied by time-resolved neutron diffraction.Journal of the American Ceramic Society,85(12),3084-3086.
MLA	E. D. Wu,et al."Intermediate phases in Ti3SiC2 synthesis from Ti/SiC/C mixtures studied by time-resolved neutron diffraction".Journal of the American Ceramic Society 85.12(2002):3084-3086.