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Amorphous-to-crystalline transformation induced by thermal annealing of a metastable Al(90)Fe(10) composite
F. Zhou; R. Luck; K. Lu; E. J. Lavernia; M. Ruhle
2002
发表期刊Philosophical Magazine a-Physics of Condensed Matter Structure Defects and Mechanical Properties
ISSN0141-8610
卷号82期号:5页码:1003-1015
摘要Crystallization from the amorphous state to metastable crystalline Al(6)Fe was induced by thermal annealing of mechanically alloyed Al(90)Fe(10) composite powders (where the composition is given in atomic per cent), which consisted of fcc Al nanocrystals in an amorphous matrix. The microstructural evolution and the transformation kinetics were characterized in detail. A thermodynamic analysis of the transformation was given, showing the nature of the polymorphous crystallization in the amorphous composite. The influence of the pre-existing crystals on crystallization was not morphologically distinctive. The observed linear kinetics law behaviour in combination with an Avrami exponent value of 2.7 +/- 0.1 suggest that the growth of a fixed nuclei population at a constant rate in three dimensions governs crystallization. The activation energy for crystallization was found to be close to the activation energy for the diffusion of Fe atoms in Al.
部门归属max planck inst met res, d-70174 stuttgart, germany. univ calif irvine, dept chem engn & mat sci, irvine, ca 92697 usa. chinese acad sci, inst met res, state key lab rapidly solidified nonequilibrium a, shenyang 110015, peoples r china.;zhou, f (reprint author), max planck inst met res, d-70174 stuttgart, germany;fzhou@uci.edu
关键词Alloys Amorphization Kinetics Glasses Powders Phases
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/36586
专题中国科学院金属研究所
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F. Zhou,R. Luck,K. Lu,et al. Amorphous-to-crystalline transformation induced by thermal annealing of a metastable Al(90)Fe(10) composite[J]. Philosophical Magazine a-Physics of Condensed Matter Structure Defects and Mechanical Properties,2002,82(5):1003-1015.
APA F. Zhou,R. Luck,K. Lu,E. J. Lavernia,&M. Ruhle.(2002).Amorphous-to-crystalline transformation induced by thermal annealing of a metastable Al(90)Fe(10) composite.Philosophical Magazine a-Physics of Condensed Matter Structure Defects and Mechanical Properties,82(5),1003-1015.
MLA F. Zhou,et al."Amorphous-to-crystalline transformation induced by thermal annealing of a metastable Al(90)Fe(10) composite".Philosophical Magazine a-Physics of Condensed Matter Structure Defects and Mechanical Properties 82.5(2002):1003-1015.
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