A new electrochemical sensor for monitoring mobile atomic hydrogen in metals | |
K. Ke; X. Y. Zhang; Y. L. Du | |
2001 | |
发表期刊 | Corrosion
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ISSN | 0010-9312 |
卷号 | 57期号:4页码:353-359 |
摘要 | A new electrochemical sensor was developed for continuous monitoring of the hydrogen content in metallic materials in engineering service at ambient temperature. The sensor is a dual electrode system, in which an electrochemically deposited nickel layer was employed as the catalyst for hydrogen oxidation, and a porous metallic oxide electrode was used as the counter electrode. No reference electrode was used in the sensor. Some effects of nickel plating and applications of the sensor were investigated. It was found that the residual anodic current of the sensor after nickel plating is possibly attributable to both oxidation of the plated nickel and discharge of the absorbed/adsorbed hydrogen atoms produced while electrodepositing nickel, but discharge of hydrogen seemed to dominate. The sensor signal responded swiftly to changes in the mobile atomic hydrogen content in metals. |
部门归属 | acad sinica, inst met res, state key lab corros & protect, shenyang 110015, peoples r china.;ke, k (reprint author), acad sinica, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110015, peoples r china |
关键词 | Electrochemical Measurement Hydrogen Permeation Hydrogen Sensor Nickel Electrodeposition |
URL | 查看原文 |
WOS记录号 | WOS:000176356100009 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/36687 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | K. Ke,X. Y. Zhang,Y. L. Du. A new electrochemical sensor for monitoring mobile atomic hydrogen in metals[J]. Corrosion,2001,57(4):353-359. |
APA | K. Ke,X. Y. Zhang,&Y. L. Du.(2001).A new electrochemical sensor for monitoring mobile atomic hydrogen in metals.Corrosion,57(4),353-359. |
MLA | K. Ke,et al."A new electrochemical sensor for monitoring mobile atomic hydrogen in metals".Corrosion 57.4(2001):353-359. |
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