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Theory of exchange interaction for heterodinuclear Mn-Ni in KZnF3 : Mn2+-Ni2+ system
X. Y. Kuang; K. W. Zhou; J. Z. Zhao
2001
Source PublicationPhysics Letters A
ISSN0375-9601
Volume285Issue:3-4Pages:177-182
AbstractAs a development of our recent works about homodinuclear clusters, a theoretical formula for describing the exchange interaction of heterodinuclear system has been derived in terms of the natural magnetic orbital method. By means of this formula and the Double-Slater-Function (DSF) calculation procedure, the various integrals in the magnetic expression have been calculated. The theoretical curve of the magnetic exchange interaction of the Mn-F-Ni cluster in KZnF3:Mn2+-Ni2+ the Mn2+-Ni2+ separation R have been obtained and the antiferromagnetic phenomenon of the heterodinuclear Mn2+-Ni2+ pair has been reasonably explained. It is shown that the contribution of kinetic exchange interaction is considerably important and that the mainly physical mechanism of the antiferromagnetic phenomenon in KZnF3:Mn2+-Ni2+ should be attributed to the combined effect of the direct exchange and kinetic exchange interactions. (C) 2001 Elsevier Science B.V, All rights reserved.
description.departmentsichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china. sichuan univ, dept phys, chengdu 610064, peoples r china. ccast, world lab, beijing 100080, peoples r china. sichuan univ, dept appl chem, chengdu 610065, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china
KeywordExchange Interaction Antiferromagnetism Complexes Spectrum Crystals Cr3++ Ions
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WOS IDWOS:000169787200011
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Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/36690
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
X. Y. Kuang,K. W. Zhou,J. Z. Zhao. Theory of exchange interaction for heterodinuclear Mn-Ni in KZnF3 : Mn2+-Ni2+ system[J]. Physics Letters A,2001,285(3-4):177-182.
APA X. Y. Kuang,K. W. Zhou,&J. Z. Zhao.(2001).Theory of exchange interaction for heterodinuclear Mn-Ni in KZnF3 : Mn2+-Ni2+ system.Physics Letters A,285(3-4),177-182.
MLA X. Y. Kuang,et al."Theory of exchange interaction for heterodinuclear Mn-Ni in KZnF3 : Mn2+-Ni2+ system".Physics Letters A 285.3-4(2001):177-182.
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