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Effect of PVC on the diffusing behavior of water through alkyd coatings
B. Liu; Y. Li; H. C. Lin; C. N. Cao
2001
发表期刊Acta Physico-Chimica Sinica
ISSN1000-6818
卷号17期号:3页码:241-244
摘要The diffusing behavior of water through alkyd coatings with different pigment volume concentration (PVC) has been studied by EIS and SEM techniques. The corresponding diffusion coefficients were also calculated. The experimental results showed that, in 0.5 mol . L-1 NaCl solution, the diffusion process of water through alkyd coatings with different PVC followed the ideal-Pick's law in the initial period. Within the PVC value concerned, the diffusion coefficients initially decreased with the increase of PVC parameter, reaching a minimum value at 60 %, which is the CPVC of micaceous iron oxide, and then increased with the PVC increase. When the PVC was less than CPVC, the barrier property produced by the pigment was the main factor that affected the water diffusion behavior. However, the microstructure of the alkyd coatings played an important role when the PVC was greater than CPVC.
部门归属chinese acad sci, inst met res, state key lab corros & protect met, shenyang 110015, peoples r china.;li, y (reprint author), chinese acad sci, inst met res, state key lab corros & protect met, shenyang 110015, peoples r china
关键词Electrochemical Impedance Spectroscopy (Eis) Sem Pigment Volume (Pvc) Alkyd Coatings Diffusion Behavior Diffusion Coefficient Different Paint Systems Barrier Properties Fickian Diffusion Films
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WOS记录号WOS:000167649400011
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被引频次:17[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/36712
专题中国科学院金属研究所
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B. Liu,Y. Li,H. C. Lin,et al. Effect of PVC on the diffusing behavior of water through alkyd coatings[J]. Acta Physico-Chimica Sinica,2001,17(3):241-244.
APA B. Liu,Y. Li,H. C. Lin,&C. N. Cao.(2001).Effect of PVC on the diffusing behavior of water through alkyd coatings.Acta Physico-Chimica Sinica,17(3),241-244.
MLA B. Liu,et al."Effect of PVC on the diffusing behavior of water through alkyd coatings".Acta Physico-Chimica Sinica 17.3(2001):241-244.
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