| A study of PrGa1-xMgxO3 as the electrolytes of SOFCs | |
| Z. G. Liu; X. Q. Huang; W. Liu; Z. Lu; J. Yuan; L. Pei; T. M. He; W. H. Su | |
| 2001 | |
| Source Publication | Chemical Journal of Chinese Universities-Chinese
 |
| ISSN | 0251-0790 |
| Volume | 22Issue:8Pages:1283-1285 |
| Abstract | PrGa1-xMgxO3(x=0, 0. 05, 0. 10, 0. 15, 0. 20, 0. 25) were synthesized by using a standard solid state technology. XRD results show that all samples are orthorhombic. Mg-doping increases the oxygen ion conductivity and decreases the activation energy of the samples significantly. The conductivity of the samples is mainly ionic. PrGa0.9Mg0.1O3 has the highest conductivity of 0. 05 S/cm at 800 degreesC, while PrGa0.8Mg0.2O3 has the lowest activation energy of 24. 19 kJ/mol in all the samples. The oxygen ion transport number of the samples increases with increasing temperature. SOFCs results show that PrGa0.9Mg0.1O3 has the best properties, for which the power density of 0. 131 W/cm(2) and the short circuit current density of 0. 45 A/cm(2) were achieved at 940 degreesC. This study reveals that Mg doped PrGaO3 is a kind of solid electrolyte with superior properties. |
| description.department | jilin univ, dept phys, changchun 130023, peoples r china. jilin univ, state key lab inorgan synth & preparat chem, changchun 130023, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;su, wh (reprint author), jilin univ, dept phys, changchun 130023, peoples r china |
| Keyword | Prgao3 Solid Electrolyte Oxygen Ion Conductivity Solid Oxide Fuel Cell Perovskite-type Oxide Fuel-cell Conductivity Anode |
| URL | 查看原文 |
| WOS ID | WOS:000170638100003 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/36732 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | Z. G. Liu,X. Q. Huang,W. Liu,et al. A study of PrGa1-xMgxO3 as the electrolytes of SOFCs[J]. Chemical Journal of Chinese Universities-Chinese,2001,22(8):1283-1285. |
| APA | Z. G. Liu.,X. Q. Huang.,W. Liu.,Z. Lu.,J. Yuan.,...&W. H. Su.(2001).A study of PrGa1-xMgxO3 as the electrolytes of SOFCs.Chemical Journal of Chinese Universities-Chinese,22(8),1283-1285. |
| MLA | Z. G. Liu,et al."A study of PrGa1-xMgxO3 as the electrolytes of SOFCs".Chemical Journal of Chinese Universities-Chinese 22.8(2001):1283-1285. |
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