Energy spectra, g factors and their pressure-induced and/or thermal shifts of SrTiO3 : Cr3+ and SrTiO3 : Mn4+I: Energy spectra and g factors at normal pressure

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	Energy spectra, g factors and their pressure-induced and/or thermal shifts of SrTiO3 : Cr3+ and SrTiO3 : Mn4+I: Energy spectra and g factors at normal pressure
	J. P. Zhang; D. P. Ma
	2001
发表期刊	Communications in Theoretical Physics
ISSN	0253-6102
卷号	35 期号:4 页码:491-496
摘要	With the strong-field scheme and cubic bases, the complete d(3) energy matrix in a tetragonally distorted cubic-field has been constructed. By diagonalizing this matrix, the energy spectra of SrTiO3:Cr3+ and SrTiO3:Mn4+ at normal pressure and various temperatures have been calculated. Correspondingly, the FORTRAN program calculating the g factor of the ground state has been worked out. By using the program and the wave function obtained from diagonalizing the complete energy matrix, the g factors of the ground state of SrTiO3:Cr3+ and SrTiO3:Mn4+ at normal pressure and room temperature have been evaluated. The calculated results are in good agreement with the optical spectral and EPR experimental data. The comparison and analysis of the results of two crystals have been made. It is demonstrated that the covalency of the bonding between Mn4+ and ligands (O2-) in SrTiO3:Mn4+ is stronger than the one of the bonding between Cr3+ and ligands (O2-) in SrTiO3:Cr3+. It is shown that the obtained wavefunctions and values of parameters are reasonable.
部门归属	sichuan univ, dept appl phys, chengdu 610065, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china.;zhang, jp (reprint author), sichuan univ, dept appl phys, chengdu 610065, peoples r china
关键词	Crystal Fields Energy Spectrum Optical Properties g Factors Covalency Ruby
URL	查看原文
WOS记录号	WOS:000168939700022
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/36898
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	J. P. Zhang,D. P. Ma. Energy spectra, g factors and their pressure-induced and/or thermal shifts of SrTiO3 : Cr3+ and SrTiO3 : Mn4+I: Energy spectra and g factors at normal pressure[J]. Communications in Theoretical Physics,2001,35(4):491-496.
APA	J. P. Zhang,&D. P. Ma.(2001).Energy spectra, g factors and their pressure-induced and/or thermal shifts of SrTiO3 : Cr3+ and SrTiO3 : Mn4+I: Energy spectra and g factors at normal pressure.Communications in Theoretical Physics,35(4),491-496.
MLA	J. P. Zhang,et al."Energy spectra, g factors and their pressure-induced and/or thermal shifts of SrTiO3 : Cr3+ and SrTiO3 : Mn4+I: Energy spectra and g factors at normal pressure".Communications in Theoretical Physics 35.4(2001):491-496.