Studies of zero-field splitting and its pressure and stress dependence for Ni2+ in La2Mg3(NO3)(12) center dot 24 H2O crystal | |
W. C. Zheng; S. Y. Wu; H. N. Dong | |
2001 | |
发表期刊 | Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences
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ISSN | 0932-0784 |
卷号 | 56期号:12页码:855-858 |
摘要 | By using the high-order perturbation formulas, the g factors gvertical barvertical bar and gperpendicular to, the zero-field splittings D and the pressure and uniaxial stress dependences of zero-field splitting are studied for Ni2+ ions in both Mg2+ sites of La2Mg3(NO3)(12) . 24H(2)O crystal. It is found that the local trigonal distortion angles 2 of the two Ni2+ centers are only slightly different from the corresponding host ones, but the local angular compressibilities under pressure and stress for both Ni2+ centers are quite different not only from the corresponding host ones, but also from each other. |
部门归属 | sichuan univ, dept mat sci, chengdu 610064, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. sichuan univ, key lab radiat phys & technol, minist educ, chengdu 610064, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china |
关键词 | La2mg3(No3)(12) Center Dot 24 H2o Ni2++ Epr Local Distortion Local Compressibility Crystal Field Theory Superposition Model Cr3++ Ions Compressibilities Impurity Pyrope |
URL | 查看原文 |
WOS记录号 | WOS:000173807200010 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/36947 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,S. Y. Wu,H. N. Dong. Studies of zero-field splitting and its pressure and stress dependence for Ni2+ in La2Mg3(NO3)(12) center dot 24 H2O crystal[J]. Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,2001,56(12):855-858. |
APA | W. C. Zheng,S. Y. Wu,&H. N. Dong.(2001).Studies of zero-field splitting and its pressure and stress dependence for Ni2+ in La2Mg3(NO3)(12) center dot 24 H2O crystal.Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences,56(12),855-858. |
MLA | W. C. Zheng,et al."Studies of zero-field splitting and its pressure and stress dependence for Ni2+ in La2Mg3(NO3)(12) center dot 24 H2O crystal".Zeitschrift Fur Naturforschung Section a-a Journal of Physical Sciences 56.12(2001):855-858. |
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