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Effect of the theta-alpha-Al2O3 transformation in scales on the oxidation behavior of a nickel-base superalloy with an aluminide diffusion coating
T. F. An; H. R. Guan; X. F. Sun; Z. Q. Hu
2000
发表期刊Oxidation of Metals
ISSN0030-770X
卷号54期号:3-4页码:301-316
摘要The high-temperature oxidation behavior of a nickel-base superalloy and aluminide-diffusion coating has been investigated over the temperature range from 800-1100 degrees C and analyzed by TGA, XRD, EDAX, and SEM. The beta-NiAl coating was formed by low-pressure gas-phase cementation at 950 degrees C for 3 hr. It was found that the formation of alpha-Al2O3 from theta-Al2O3 on the beta-NiAl coating resulted in a sharp decrease in the parabolic rate constant k(p) by one order of magnitude at 1050 degrees C during transient oxidation. The transformation caused the anomalous behavior of the oxidation kinetics curves of this diffusion coating in the temperature range 800-1100 degrees C within the first 100 hr. A change in the morphology of scales also occurred with the transformation. A growth stress was characterized by the formation of convoluted scales, which were observed on the surface after oxidation. The oxidation mechanism of this beta-NiAl diffusion coating is described.
部门归属chinese acad sci, inst met res, lab superalloy & special casting, shenyang 110015, peoples r china. chinese acad sci, met res inst, state key lab fatigue & fracture mat, shenyang 110015, peoples r china.;an, tf (reprint author), chinese acad sci, inst met res, lab superalloy & special casting, shenhe dist, shenyang 110015, peoples r china
关键词Beta-nial Diffusion Coating Alpha-al2o3 Theta-al2o3 Oxidation Mechanism Al-y Alloys Fe-cr-al Intergranular Oxidation Transient Oxidation High-temperature Morphology Mechanisms Yttrium
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WOS记录号WOS:000088799600007
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被引频次:107[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/36968
专题中国科学院金属研究所
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T. F. An,H. R. Guan,X. F. Sun,et al. Effect of the theta-alpha-Al2O3 transformation in scales on the oxidation behavior of a nickel-base superalloy with an aluminide diffusion coating[J]. Oxidation of Metals,2000,54(3-4):301-316.
APA T. F. An,H. R. Guan,X. F. Sun,&Z. Q. Hu.(2000).Effect of the theta-alpha-Al2O3 transformation in scales on the oxidation behavior of a nickel-base superalloy with an aluminide diffusion coating.Oxidation of Metals,54(3-4),301-316.
MLA T. F. An,et al."Effect of the theta-alpha-Al2O3 transformation in scales on the oxidation behavior of a nickel-base superalloy with an aluminide diffusion coating".Oxidation of Metals 54.3-4(2000):301-316.
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