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The effect of Ti/Al ratio on the site occupancies of alloying elements in gamma-TiAl
Y. L. Hao; R. Yang; Y. Y. Cui; D. Li
2000
发表期刊Intermetallics
ISSN0966-9795
卷号8期号:5-6页码:633-636
摘要The site occupancies of V, Cr, Mn, Fe, Ni, Zr, Nb, Ta, Mo, Ga and Sn (1 similar to 5 at%) in TiAl alloys with different nominal Ti/Al ratios were measured by the atom location channelling enhanced microanalysis (ALCHEMI) method. The results showed that Zr, Nb and Ta invariably occupy Ti sublattice sites, whereas Fe, Ni, Ga and Sn occupy Al sublattice sites, the alloy composition having no significant influence on their site preference. By contrast, the site preference of V, Cr, and Mn changes significantly with alloy composition (the Ti/ Al ratio in particular), the probability of these elements occupying Ti sites decreasing in the above order. In general, with increasing atomic number, elements in the same period show increasing tendency to substitute for Al, so is the tendency to substitute for Ti for elements in the same group of the periodic table. A discussion is made in terms of the Bragg-Williams model by using published bond order data as input, allowing qualitative interpretation of the experimental findings. (C) 2000 Elsevier Science Ltd. All rights reserved.
部门归属acad sinica, inst met res, shenyang 110015, peoples r china.;yang, r (reprint author), acad sinica, inst met res, 72 wenhua rd, shenyang 110015, peoples r china
关键词Titanium Aluminides Based On Tial Crystal Chemistry Of Intermetallics Site Occupancy Beam Electron-diffraction Ternary Additions Base Alloys Cr Location Compound Alchemi Ti3al Mn Behavior
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WOS记录号WOS:000087393800030
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被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/37041
专题中国科学院金属研究所
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Y. L. Hao,R. Yang,Y. Y. Cui,et al. The effect of Ti/Al ratio on the site occupancies of alloying elements in gamma-TiAl[J]. Intermetallics,2000,8(5-6):633-636.
APA Y. L. Hao,R. Yang,Y. Y. Cui,&D. Li.(2000).The effect of Ti/Al ratio on the site occupancies of alloying elements in gamma-TiAl.Intermetallics,8(5-6),633-636.
MLA Y. L. Hao,et al."The effect of Ti/Al ratio on the site occupancies of alloying elements in gamma-TiAl".Intermetallics 8.5-6(2000):633-636.
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