High temperature scaling of two-phase Fe-Cu alloys under low oxygen pressures

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	High temperature scaling of two-phase Fe-Cu alloys under low oxygen pressures
	Y. Niu; Y. S. Li; F. Gesmundo
	2000
发表期刊	Corrosion Science
ISSN	0010-938X
卷号	42 期号:1 页码:165-181
摘要	The oxidation of binary two-phase Fe-Cu alloys containing 25, 50 and 75 wt% Cu and composed of mixtures of the two terminal solid solutions of copper in iron and iron in copper has been studied at 800-900 degrees C under oxygen pressures below the stability of copper oxides. The oxidation followed the parabolic law only in some cases, while in others it was rather irregular. The scaling rates of the alloys were lower than for pure iron and decreased with an increase in the copper content under constant temperature. The scales were always composed of an inner layer containing a mixture of copper metal and iron oxide and of an outer layer of iron oxide with very little dissolved copper. The interface between the two layers was generally regular and corresponded approximately to the location of the original alloys surface, while the distribution of the two phases in the mixed region followed closely that of the two metal phases in the original alloys. No significant iron depletion was observed in the alloys beneath the region of internal oxidation. The peculiar scale microstructures observed for these alloys are mainly a result of the limited mutual solubility of the two components and of their special microstructures involving the presence of two phases of widely different composition. (C) 1999 Elsevier Science Ltd. All rights reserved.
部门归属	univ genoa, ist chim, i-16129 genoa, italy. chinese acad sci, inst corros & protect met, state key lab corros & protect, shenyang 110015, peoples r china.;gesmundo, f (reprint author), univ genoa, ist chim, fiera del mare,pad d, i-16129 genoa, italy
关键词	Copper Iron Oxidation Low Oxygen Pressures High Temperatures 2-phase Binary-alloys Co-nb Alloys Low Oxidant Pressures 1 Atm O-2 Internal Oxidation H2-h2s Mixtures 600-800-degrees-c Corrosion Sulfidation 600-degrees-c-800-degrees-c
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WOS记录号	WOS:000084273400011
引用统计	被引频次：39[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37141
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Niu,Y. S. Li,F. Gesmundo. High temperature scaling of two-phase Fe-Cu alloys under low oxygen pressures[J]. Corrosion Science,2000,42(1):165-181.
APA	Y. Niu,Y. S. Li,&F. Gesmundo.(2000).High temperature scaling of two-phase Fe-Cu alloys under low oxygen pressures.Corrosion Science,42(1),165-181.
MLA	Y. Niu,et al."High temperature scaling of two-phase Fe-Cu alloys under low oxygen pressures".Corrosion Science 42.1(2000):165-181.