Investigations of the g factors for Co2+ in fluoroperovskites

IMR OpenIR

	Investigations of the g factors for Co2+ in fluoroperovskites
	W. C. Zheng; P. Ren; S. Y. Wu
	2000
发表期刊	Physica B-Condensed Matter
ISSN	0921-4526
卷号	291 期号:1-2 页码:123-127
摘要	The perturbation formula of g factor for 3d(7) ion in cubic octahedral crystals has been obtained from a cluster approach. In the formula, the parameters related to the configuration interaction and the covalency reduction effect can be obtained from the optical spectra of the crystal under study and so no adjustable parameters are applied. From the formula, the g factors for Co2+ in fluoroperovskites LiBaF3, KMBF3, KZnF3 and CsCdF3 are calculated. The calculated results are in agreement with the observed values. The g factor following the order of LiBaF3 : Co2+ < KMgF3 : Co2+ < KZnF3: Co2+ < CsCdF3 : Co2+ is also explained. (C) 2000 Elsevier Science B.V. All rights reserved.
部门归属	sichuan univ, dept mat sci, chengdu 610064, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china
关键词	Electron Paramagnetic Resonance Crystal- And ligAnd-field Theory Co2++ Libaf3 Kmgf3 Kznf3 Cscdf3 Perovskite Transition Impurities Crystals
URL	查看原文
WOS记录号	WOS:000088686000018
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37281
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. C. Zheng,P. Ren,S. Y. Wu. Investigations of the g factors for Co2+ in fluoroperovskites[J]. Physica B-Condensed Matter,2000,291(1-2):123-127.
APA	W. C. Zheng,P. Ren,&S. Y. Wu.(2000).Investigations of the g factors for Co2+ in fluoroperovskites.Physica B-Condensed Matter,291(1-2),123-127.
MLA	W. C. Zheng,et al."Investigations of the g factors for Co2+ in fluoroperovskites".Physica B-Condensed Matter 291.1-2(2000):123-127.