The sulfidation of two-phase Fe-Cu alloys in H-2-H2S mixtures at 500-700 degrees C

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	The sulfidation of two-phase Fe-Cu alloys in H-2-H2S mixtures at 500-700 degrees C
	P. Castello; Y. Niu; F. Gesmundo; F. H. Stott
	1999
发表期刊	Oxidation of Metals
ISSN	0030-770X
卷号	52 期号:5-6 页码:403-426
摘要	The sulfidation behavior of three two-phase Fe-Cu alloys containing 25, 50, and 75 wt.% copper has been investigated in H-2-H2S mixtures at 500-700 degrees C under gas-phase sulfur pressures, which is significantly above those for the dissociation of both FeS and Cu2S. In all cases, the three alloys sulfidized more slowly than both pure metals under the same conditions. At all temperatures, Fe-25Cu showed the slowest growth rates, whereas Fe-50Cu sulfidized more rapidly than the other two alloys. However, the kinetics curves for the three alloys tended to over lap, particularly at the higher temperatures. The scales were complex and contained an outer layer composed of a mixture of two different Cu-Fe double sulfides, Cu5FeS4 and CuFeS2, plus an inner zone containing a mixture of metallic iron with the double sulfide Cu5FeS4 formed by complete sulfidation of the copper-rich phase anti partial sulfidation of the iron-rick phase. This region also contained large voids, possibly because of outward diffusion of metal cations, whereas the iron-rich islands were mainly unattacked. The depth of intrenal attack increased with increasing temperature and/or iron content. Finally, particles of almost pure copper metal, probably formed during cooling from the reaction temperature,,were present at the scale-subscale interface, as inclusions in the scale and as whiskers producing out of the external scale surface.
部门归属	univ genoa, ist chim, i-16129 genoa, italy. inst corros & protect met, state key lab corros & protect, shenyang 110015, peoples r china. univ manchester, inst sci & technol, ctr corros & protect, manchester m60 1qd, lancs, england.;castello, p (reprint author), univ genoa, ist chim, pad d, i-16129 genoa, italy
关键词	Sulfidation Iron-copper Two-phase Alloys 2-phase Binary-alloys Ni-nb Alloys High-temperature Oxidation Most-reactive Component Possible Scaling Modes Low Oxidant Pressures Low-oxygen Pressures 1 Atm O-2 H2-h2s Mixtures Air Oxidation
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WOS记录号	WOS:000082060400003
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37310
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	P. Castello,Y. Niu,F. Gesmundo,et al. The sulfidation of two-phase Fe-Cu alloys in H-2-H2S mixtures at 500-700 degrees C[J]. Oxidation of Metals,1999,52(5-6):403-426.
APA	P. Castello,Y. Niu,F. Gesmundo,&F. H. Stott.(1999).The sulfidation of two-phase Fe-Cu alloys in H-2-H2S mixtures at 500-700 degrees C.Oxidation of Metals,52(5-6),403-426.
MLA	P. Castello,et al."The sulfidation of two-phase Fe-Cu alloys in H-2-H2S mixtures at 500-700 degrees C".Oxidation of Metals 52.5-6(1999):403-426.