Influence of pre-annealing on the thermal stability of a nanocrystalline Hf-Ni alloy

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	Influence of pre-annealing on the thermal stability of a nanocrystalline Hf-Ni alloy
	Z. F. Dong; K. Lu; I. Bakonyi
	1999
发表期刊	Nanostructured Materials
ISSN	0965-9773
卷号	11 期号:2 页码:187-194
摘要	A nanocrystalline (NC) sample was prepared by quenching a Hf11Ni89 alloy with the melt-pinning technique A randomly oriented HfNi5, nanophase with an average grain size of about 10 nm was formed by this process A an extension of our previous work on the as-quenched state of this NC Hf-Ni alloy, here we use DSC and XRD to report on a thermal stability study of samples pre-annealed at 340 degrees C for different periods of time t(a) up to 510 min. Thc pre-annealing was performed under conditions: that did not result in a change of the grain size. Similarly to the as-quenched state of the NC HfNi5 alloy, two exothermal peaks appear in the DSC curve for the pre-annealed NC samples on heating at a constant heating rate. The two peaks may also be attributed to a grain-growth process of the HfNi5 nanophase prior to a precipitation process of a Ni solid solution phase. Activation energies for the two processes were calculated by using the Kissinger equation, It was obtained that a pre-annealing treatment decreases the thermal stability of the NC sample, which was characterized by a reduction of the temperatures and the activation energies for thr grain-growth and the Ni precipitation processes. The DSC analysis revealed that the total excess energy of this highly non-equilibrium alloy and, specifically, the grain-boundary energy, decrease with increasing pre-annealing time. These changes in the parameters characterizing the thermal stability of the NC HfNi5 alloy are discussed on the basis of observed modifications of the microstructure with the help of atomic diffusion processes and, also, of magnetic measurements on pre-annealed samples described elsewhere. (C) 1999 Acta Metallurgica Inc.
部门归属	chinese acad sci, inst phys, beijing lab electron microscopy, beijing 100080, peoples r china. chinese acad sci, ctr condensed matter phys, beijing 100080, peoples r china. chinese acad sci, inst met res, state key lab rsa, shenyang 110015, peoples r china. hungarian acad sci, res inst solid state phys & opt, h-1525 budapest, hungary.;dong, zf (reprint author), univ wisconsin, dept mat sci & engn, 1500 engn dr erb, madison, wi 53706 usa
关键词	Differential Scanning Calorimetry Melt-quenched Ribbons Grain-growth Electron-microscopy p Alloys Magnetic-properties Physical-properties Fe-rich Co-rich Zr
URL	查看原文
WOS记录号	WOS:000081172200004
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37349
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Z. F. Dong,K. Lu,I. Bakonyi. Influence of pre-annealing on the thermal stability of a nanocrystalline Hf-Ni alloy[J]. Nanostructured Materials,1999,11(2):187-194.
APA	Z. F. Dong,K. Lu,&I. Bakonyi.(1999).Influence of pre-annealing on the thermal stability of a nanocrystalline Hf-Ni alloy.Nanostructured Materials,11(2),187-194.
MLA	Z. F. Dong,et al."Influence of pre-annealing on the thermal stability of a nanocrystalline Hf-Ni alloy".Nanostructured Materials 11.2(1999):187-194.