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Influence of yttrium implantation on oxidation behavior of Co-40Cr alloy at 900 degrees C
H. M. Jin; T. F. Li; M. S. Li; J. I. Shen; L. Xin; J. Y. Huang
1999
Source PublicationJournal of Rare Earths
ISSN1002-0721
Volume17Issue:1Pages:34-37
AbstractThe oxidation behavior of Co-40Cr alloy with and without yttrium implantation was studied at 900 degrees C in the air. Scanning electron microscopy(SEM), secondary ion massive spectroscopy(SIMS), transmission electron microscopy(TEM) and high resolution electron microscopy(HREM) were used to study the forming mechanism of oxide film on the alloy. It is found that the binding energy of Cr on the alloy surface is decreased by yttrium implantation, thus the formation of protective Cr2O3 film on the substrate is accelerated. In the mean time, the binding energy of Cr inside the oxide scale is increased by yttrium implantation, and this would reduce the Cr3+ cation diffusion through the film. Yttrium implantation decreases the grain size and the growing speed of oxide film. SIMS and TEM/HREM results show that some yttrium exists as small YCrO3 particles at Cr2O3 grain-boundary near the oxide/gas interface, and a few small Y2O3 particles exist near the substrate/oxide interface. Besides, yttrium may also segregate to Cr2O3 grain-boundary as Y3+, reduce Cr3+ cation diffusion and change the mechanical properties of the oxide film. The ability of anti-oxidation of Co-40Cr alloy is greatly improved by yttrium implantation.
description.departmentchinese acad sci, inst corros & protect met, state key lab corros & protect, shenyang 110015, peoples r china. chinese acad sci, inst met res, state key lab atom imaging solids, shenyang 110015, peoples r china.
KeywordRare Earths Oxide Film Binding Energy Ion implantatIon Cracking
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WOS IDWOS:000079462900009
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Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/37387
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
H. M. Jin,T. F. Li,M. S. Li,et al. Influence of yttrium implantation on oxidation behavior of Co-40Cr alloy at 900 degrees C[J]. Journal of Rare Earths,1999,17(1):34-37.
APA H. M. Jin,T. F. Li,M. S. Li,J. I. Shen,L. Xin,&J. Y. Huang.(1999).Influence of yttrium implantation on oxidation behavior of Co-40Cr alloy at 900 degrees C.Journal of Rare Earths,17(1),34-37.
MLA H. M. Jin,et al."Influence of yttrium implantation on oxidation behavior of Co-40Cr alloy at 900 degrees C".Journal of Rare Earths 17.1(1999):34-37.
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