As an interconnector of solid oxide fuel cell, La1-xCaxCrO3(x = 0.0 similar to 0.5) were prepared by sol-gel method. The crystal structures of La1-xCaxCrO3 at room temperature are the orthorhombic perovskite GdFeO3-type. XPS analysis indicates that chrome ions are in different valence state. The introduction of Ca2+ into the lattice induces the oxidation of Cr3+ to Cr6+. With x increasing, the amount of Cr6+ increases. The present of the more Cr6+ is one of the important factors that effect electric conductivity of La1-xCaxCrO3.
部门归属
jilin univ, grp rare earth solid state phys, changchun 130023, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china. china ctr adv sci & technol, ctr condensed matter & radiat phys, beijing 100080, peoples r china.
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