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Energy spectrum and g factors of alpha-Al2O3 : Ni2+ and their pressure-induced shifts
D. P. Ma; X. D. Ma; J. R. Chen; Y. Y. Liu
1999
发表期刊Communications in Theoretical Physics
ISSN0253-6102
卷号31期号:1页码:39-48
摘要A unified calculation of the whole energy spectrum and g factors of the ground state at normal pressure and their pressure-induced shifts for alpha-Al2O3:Ni2+ has been carried out on the basis of the theory of pressure-induced shifts and the diagonalization of the complete d(8) energy matrix adopting C-3 upsilon symmetry. The calculated results are in very good agreement with all the experimental data. The rates of change of all the levels with respect to various parameters and the contributions to typical levels or splittings from various parameters have been calculated. The distinct differences of pressure-induced shifts of various levels are immediately determined by their characteristic dependencies on the parameters of interactions, and the pressure-induced shifts (especially those of t(2)(6)e(2) E-1 (E) over cap) have provided important or crucial criteria for the correctness of the calculation and assignment of the energy spectrum of alpha-Al2O3:Ni2+.
部门归属chengdu univ sci & technol, dept phys, chengdu 610065, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;ma, dp (reprint author), chengdu univ sci & technol, dept phys, chengdu 610065, peoples r china
关键词Crystal Fields Energy Spectrum g Factor High-pressure Effects Theoretical Calculations Ruby
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WOS记录号WOS:000079463600007
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/37451
专题中国科学院金属研究所
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D. P. Ma,X. D. Ma,J. R. Chen,et al. Energy spectrum and g factors of alpha-Al2O3 : Ni2+ and their pressure-induced shifts[J]. Communications in Theoretical Physics,1999,31(1):39-48.
APA D. P. Ma,X. D. Ma,J. R. Chen,&Y. Y. Liu.(1999).Energy spectrum and g factors of alpha-Al2O3 : Ni2+ and their pressure-induced shifts.Communications in Theoretical Physics,31(1),39-48.
MLA D. P. Ma,et al."Energy spectrum and g factors of alpha-Al2O3 : Ni2+ and their pressure-induced shifts".Communications in Theoretical Physics 31.1(1999):39-48.
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