| Local phase-transition behaviour for Fe3+ and Gd3+ in RbCdF3 and RbCaF3 crystals |
| W. C. Zheng; S. Wu
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| 1999
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发表期刊 | Physica B-Condensed Matter
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ISSN | 0921-4526
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卷号 | 271期号:1-4页码:248-251 |
摘要 | In this paper, the local release factor k, which is introduced to characterize the release or elongation effect of the impurity-ligand bond along the C-4-axis at the cubic-to-tetragonal phase transition, is studied for Fe3+ and Gd3+ in RbCdF3 and RbCaF3 crystals by analysing the EPR data. From the studies, it is found that, similar to the local rotational order parameter phi, the local release factor k is different from the corresponding intrinsic release factor ii,,, of the host crystal as well as from impurity to impurity. It appears that the impurity ion call influence the local phase-transition behaviour in the vicinity of the impurity ion in the doped crystals. (C) 1999 Elsevier Science B.V. All rights reserved. |
部门归属 | sichuan univ, dept mat sci, chengdu 610064, peoples r china. chinese acad sci, int ctr mat phys, shenyang 110015, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china
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关键词 | Local Phase-transition Behaviour
Electron Paramagnetic Resonance
Fe3++
Gd3++
Rbcdf3
Rbcaf3
Endor
Splittings
Centers
Epr
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URL | 查看原文
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WOS记录号 | WOS:000084152100026
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引用统计 |
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文献类型 | 期刊论文
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条目标识符 | http://ir.imr.ac.cn/handle/321006/37600
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专题 | 中国科学院金属研究所
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推荐引用方式 GB/T 7714 |
W. C. Zheng,S. Wu. Local phase-transition behaviour for Fe3+ and Gd3+ in RbCdF3 and RbCaF3 crystals[J]. Physica B-Condensed Matter,1999,271(1-4):248-251.
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APA |
W. C. Zheng,&S. Wu.(1999).Local phase-transition behaviour for Fe3+ and Gd3+ in RbCdF3 and RbCaF3 crystals.Physica B-Condensed Matter,271(1-4),248-251.
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MLA |
W. C. Zheng,et al."Local phase-transition behaviour for Fe3+ and Gd3+ in RbCdF3 and RbCaF3 crystals".Physica B-Condensed Matter 271.1-4(1999):248-251.
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