Phase relations in the system BiO1.5-YbO1.5-CuO

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	Phase relations in the system BiO1.5-YbO1.5-CuO; Phase relations in the system BiO1.5-YbO1.5-CuO
	X. L. Chen; F. F. Zhang; Y. M. Shen; J. K. Liang; W. H. Tang; Q. Y. Tu
	1998 ; 1998
发表期刊	Journal of Solid State Chemistry ; Journal of Solid State Chemistry
ISSN	0022-4596 ; 0022-4596
卷号	139 期号:2 页码:398-403
摘要	The subsolidus phase relations for the ternary system, BiO1.5YbO1.5-CuO, are investigated by the powder X-ray diffraction method. The system can be divided into six three-phase regions and three two-phase regions. There exist two solid solutions Bi1-xYbxO1.5 (0.05 less than or equal to x less than or equal to 0.35) and Yb1-xBixO1.5 (x less than or equal to 0.02). The former solution exhibits a tetragonal structure with 0.05 less than or equal to x <0.15 which is isostructural to beta-BiO1.5, while a cubic structure with 0.15 less than or equal to x less than or equal to 0.35 is isostructural to delta-BiO1.5. A new compound with the composition close to Yb12Bi12CuOy. is found. (C) 1998 Academic Press.; The subsolidus phase relations for the ternary system, BiO1.5YbO1.5-CuO, are investigated by the powder X-ray diffraction method. The system can be divided into six three-phase regions and three two-phase regions. There exist two solid solutions Bi1-xYbxO1.5 (0.05 less than or equal to x less than or equal to 0.35) and Yb1-xBixO1.5 (x less than or equal to 0.02). The former solution exhibits a tetragonal structure with 0.05 less than or equal to x <0.15 which is isostructural to beta-BiO1.5, while a cubic structure with 0.15 less than or equal to x less than or equal to 0.35 is isostructural to delta-BiO1.5. A new compound with the composition close to Yb12Bi12CuOy. is found. (C) 1998 Academic Press.
部门归属	chinese acad sci, inst phys, beijing 100080, peoples r china. chinese acad sci, ctr condensed matter phys, beijing 100080, peoples r china. beijing normal univ, dept phys, beijing 100875, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;chen, xl (reprint author), chinese acad sci, inst phys, pob 603, beijing 100080, peoples r china ; chinese acad sci, inst phys, beijing 100080, peoples r china. chinese acad sci, ctr condensed matter phys, beijing 100080, peoples r china. beijing normal univ, dept phys, beijing 100875, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;chen, xl (reprint author), chinese acad sci, inst phys, pob 603, beijing 100080, peoples r china
关键词	Diffraction Data Diffraction Data Beta-bi2o3 Beta-bi2o3
URL	查看原文 ; 查看原文
WOS记录号	WOS:000075921600024 ; WOS:000075921600024
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37641
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. L. Chen,F. F. Zhang,Y. M. Shen,et al. Phase relations in the system BiO1.5-YbO1.5-CuO, Phase relations in the system BiO1.5-YbO1.5-CuO[J]. Journal of Solid State Chemistry, Journal of Solid State Chemistry,1998, 1998,139, 139(2):398-403, 398-403.
APA	X. L. Chen,F. F. Zhang,Y. M. Shen,J. K. Liang,W. H. Tang,&Q. Y. Tu.(1998).Phase relations in the system BiO1.5-YbO1.5-CuO.Journal of Solid State Chemistry,139(2),398-403.
MLA	X. L. Chen,et al."Phase relations in the system BiO1.5-YbO1.5-CuO".Journal of Solid State Chemistry 139.2(1998):398-403.