The oxidation of two Fe-Y alloys under low oxygen pressures at 600-800 degrees C

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	The oxidation of two Fe-Y alloys under low oxygen pressures at 600-800 degrees C
	Y. Niu; R. Y. Yan; G. Y. Fu; W. T. Wu; F. Gesmundo
	1998
发表期刊	Oxidation of Metals
ISSN	0030-770X
卷号	49 期号:1-2 页码:91-114
摘要	The corrosion of pure yttrium and of two Fe-base alloys containing approximately 15 and 30 wt.% Y was studied at 600-800 degrees C in H-2-CO2 mixtures providing an equilibrium oxygen pressure of 10(-24) atm 600 degrees C and 10(-20) atm at 700 and 800 degrees C. The corrosion of yttrium under these low oxygen pressures resulted in the growth of Y2O3 scales and presented two approximately parabolic stages at 800 degrees C, while at 600-700 degrees C it was faster and nonprotective. The corrosion of the two alloys followed approximately the parabolic rare law, except for Fe-15Y at 600 degrees C which oxidized nearly linearly. At 600 and 700 degrees C, when the gas-phase oxygen pressure was in the field of stability of iron oxide, the alloys formed also a thin external Fe3O4 layer, while at 800 degrees C, when the oxygen pressure was below the stability of FeO, a thin outermost layer of pure iron was observed to form. Under all conditions a region of internal oxidation formed in the alloy, in which the yttrium-rich phases were transformed into a mixture of iron metal and oxides, which included double Fe-Y oxides as well as Y2O3. The microstructure of the internal-oxidation region followed closely that of the original alloys, which moreover did not undergo any yttrium depletion. These results are examined by taking into account the low solubility of yttrium ib iron and the presence of intermetallic compounds in the alloys.
部门归属	acad sinica, inst corros & protect, state key lab corros & protect, shenyang 110015, peoples r china. univ genoa, fac ingn, ist chim, i-16129 genoa, italy. shenyang inst chem engn, shenyang 110021, peoples r china.;niu, y (reprint author), acad sinica, inst corros & protect, state key lab corros & protect, wencui rd 62, shenyang 110015, peoples r china
关键词	Iron Yttrium Alloys Internal Oxidation 2-phase Binary-alloys High-temperature Oxidation Most-reactive Component Possible Scaling Modes Low Oxidant Pressures Internal Oxidation Al Alloys A/o Al Corrosion 1173-k
URL	查看原文
WOS记录号	WOS:000072410200005
引用统计	被引频次：17[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37745
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Niu,R. Y. Yan,G. Y. Fu,et al. The oxidation of two Fe-Y alloys under low oxygen pressures at 600-800 degrees C[J]. Oxidation of Metals,1998,49(1-2):91-114.
APA	Y. Niu,R. Y. Yan,G. Y. Fu,W. T. Wu,&F. Gesmundo.(1998).The oxidation of two Fe-Y alloys under low oxygen pressures at 600-800 degrees C.Oxidation of Metals,49(1-2),91-114.
MLA	Y. Niu,et al."The oxidation of two Fe-Y alloys under low oxygen pressures at 600-800 degrees C".Oxidation of Metals 49.1-2(1998):91-114.