Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5

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	Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5
	Y. Shi; J. K. Liang; H. Zhang; Q. L. Liu; X. L. Chen; J. L. Yang; W. D. Zhuang; G. H. Rao
	1998
发表期刊	Journal of Solid State Chemistry
ISSN	0022-4596
卷号	135 期号:1 页码:43-51
摘要	The crystal structure and thermal decomposition process of barium borophosphate BaBPO5 have been studied by a combination of X-ray powder diffraction (XRD) and vibration spectroscopic techniques, The structure of BaBPO5 is refined by Rietveld technique, which indicates that the structure units of this compound are PO4 and BO4 tetrahedra as well as irregular rare earth polyhedra, The thermal decomposition process of BaBPO5 have been observed by the XRD patterns of decomposition samples under a series of heat treatments, The Raman and infrared spectra of the initial compound BaBPO5 and its decomposed products Ba3BP3O12 and Ba2P2O7 showed the variations of the anion groups of boron and phosphorus, Assignments have been deduced from the systematic investigation of natural compounds and isotopic species with the help of isotopic shift data of B-10-B-11. (C) 1998 Academic Press.
部门归属	chinese acad sci, inst phys, beijing 100080, peoples r china. chinese acad sci, ctr condensed matter phys, beijing 100080, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;shi, y (reprint author), chinese acad sci, inst phys, pob 603, beijing 100080, peoples r china
关键词	Vibrational-spectra Sinhalite
URL	查看原文
WOS记录号	WOS:000072523100005
引用统计	被引频次：62[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37772
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Shi,J. K. Liang,H. Zhang,et al. Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5[J]. Journal of Solid State Chemistry,1998,135(1):43-51.
APA	Y. Shi.,J. K. Liang.,H. Zhang.,Q. L. Liu.,X. L. Chen.,...&G. H. Rao.(1998).Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5.Journal of Solid State Chemistry,135(1),43-51.
MLA	Y. Shi,et al."Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5".Journal of Solid State Chemistry 135.1(1998):43-51.