Investigation of the zero-field splitting and g factors for V2+ in CsMgCl3

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	Investigation of the zero-field splitting and g factors for V2+ in CsMgCl3
	W. C. Zheng; S. Y. Wu
	1998
发表期刊	Physica B-Condensed Matter
ISSN	0921-4526
卷号	245 期号:2 页码:123-126
摘要	In this paper, by using only one adjustable parameter V' (the trigonal-field parameter), the zero-held splitting D, the g factors g(parallel to) and Delta g (= g(parallel to) -g(perpendicular to)) for CsMgCl3:V2+ crystal have been calculated from the high-order perturbation formulas based on the two spin-orbit coupling parameter model. The calculated results show good agreement with the observed values. A comparison between the calculated results from various crystal field theories are also made. It is found that the difference between signs D and Delta g for CsMgCl3:V2+ crystal is caused by the contributions from the excited multiplets, particularly those arising from the free ionic term (2)G. (C) 1998 Elsevier Science B.V. All rights reserved.
部门归属	sichuan univ, dept mat sci, chengdu 610064, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china
关键词	Crystal And ligAnd Field Theory Electron Paramagnetic Resonance Spin-orbit Coupling V2++ Ion Csmgcl3 Crystal Spectra Ions
URL	查看原文
WOS记录号	WOS:000072756100005
引用统计	被引频次：7[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/37911
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. C. Zheng,S. Y. Wu. Investigation of the zero-field splitting and g factors for V2+ in CsMgCl3[J]. Physica B-Condensed Matter,1998,245(2):123-126.
APA	W. C. Zheng,&S. Y. Wu.(1998).Investigation of the zero-field splitting and g factors for V2+ in CsMgCl3.Physica B-Condensed Matter,245(2),123-126.
MLA	W. C. Zheng,et al."Investigation of the zero-field splitting and g factors for V2+ in CsMgCl3".Physica B-Condensed Matter 245.2(1998):123-126.