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Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals
W. C. Zheng; S. Y. Wu; W. Li
1998
发表期刊Physica B-Condensed Matter
ISSN0921-4526
卷号253期号:1-2页码:79-82
摘要This paper presents a cluster approach for the calculations of the absorption band positions and the g factor of d(2) tetrahedral cluster. In the approach, the different modifications of e and t(2) orbitals of d electrons and the contribution from the spin-orbit coupling of ligands to the EPR g factor due to the mixing of d(2) ions with the ligands are considered. The calculated band positions and g factor for ZnX : V3+ (X = S, Se, Te) crystals show good agreement with the observed values by using only two adjustable parameters. The contribution from the spin-orbit coupling of ligands to the g factor is discussed. (C) 1998 Elsevier Science B.V. All rights reserved.
部门归属sichuan univ, dept mat sci, chengdu 610064, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china
关键词Crystal- And ligAnd-field Theory V3++ Znx (x = s Optical Spectra Se Electron Paramagnetic Te) Resonance Spin-orbit Coupling Vanadium Centers Znte Crystals
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WOS记录号WOS:000075457900011
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/37914
专题中国科学院金属研究所
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W. C. Zheng,S. Y. Wu,W. Li. Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals[J]. Physica B-Condensed Matter,1998,253(1-2):79-82.
APA W. C. Zheng,S. Y. Wu,&W. Li.(1998).Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals.Physica B-Condensed Matter,253(1-2),79-82.
MLA W. C. Zheng,et al."Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals".Physica B-Condensed Matter 253.1-2(1998):79-82.
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