Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals | |
W. C. Zheng; S. Y. Wu; W. Li | |
1998 | |
发表期刊 | Physica B-Condensed Matter
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ISSN | 0921-4526 |
卷号 | 253期号:1-2页码:79-82 |
摘要 | This paper presents a cluster approach for the calculations of the absorption band positions and the g factor of d(2) tetrahedral cluster. In the approach, the different modifications of e and t(2) orbitals of d electrons and the contribution from the spin-orbit coupling of ligands to the EPR g factor due to the mixing of d(2) ions with the ligands are considered. The calculated band positions and g factor for ZnX : V3+ (X = S, Se, Te) crystals show good agreement with the observed values by using only two adjustable parameters. The contribution from the spin-orbit coupling of ligands to the g factor is discussed. (C) 1998 Elsevier Science B.V. All rights reserved. |
部门归属 | sichuan univ, dept mat sci, chengdu 610064, peoples r china. acad sinica, int ctr mat phys, shenyang 110015, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china |
关键词 | Crystal- And ligAnd-field Theory V3++ Znx (x = s Optical Spectra Se Electron Paramagnetic Te) Resonance Spin-orbit Coupling Vanadium Centers Znte Crystals |
URL | 查看原文 |
WOS记录号 | WOS:000075457900011 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/37914 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,S. Y. Wu,W. Li. Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals[J]. Physica B-Condensed Matter,1998,253(1-2):79-82. |
APA | W. C. Zheng,S. Y. Wu,&W. Li.(1998).Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals.Physica B-Condensed Matter,253(1-2),79-82. |
MLA | W. C. Zheng,et al."Explanations of the optical spectra and g factor for V3+ ions in ZnX (X = S, Se, Te) crystals".Physica B-Condensed Matter 253.1-2(1998):79-82. |
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