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The synthesis of La0.875-xEuxNa0.125CrO3 and its study by Eu-151 Mossbauer spectroscopy
L. P. Li; Q. A. Wei; Z. J. Kang; M. Q. Rui; W. H. Su
1997
发表期刊Journal of Alloys and Compounds
ISSN0925-8388
卷号249期号:1-2页码:264-267
摘要The perovskite oxides La0.875-xEuxNa0.125CrO3 were prepared at 1200 degrees C by solid state reaction. XRD, XPS and Eu-151 Mossbauer spectra measurements show that the structures are orthorhombic and their lattice distortion degree increases with x. Cr ions are in mixed valence of +3 and +6. With x increasing, the amount of Cr6+ becomes larger. The covalency and length of Eu-O bonds are the most important factors influencing the isomer shift of Eu-151.
部门归属jilin univ,ctr anal & measurement,changchun 130023,peoples r china. jilin univ,dept chem,changchun 130023,peoples r china. acad sinica,int ctr mat phys,shenyang 110015,peoples r china.;li, lp (reprint author), jilin univ,dept phys,changchun 130023,peoples r china
关键词La0.875-xeuxna0.125cro3 Eu-151 Mossbauer Spectra Xps Valence Fluctuation Isomer Shift Oxides Chromites Spectra
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/38000
专题中国科学院金属研究所
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L. P. Li,Q. A. Wei,Z. J. Kang,et al. The synthesis of La0.875-xEuxNa0.125CrO3 and its study by Eu-151 Mossbauer spectroscopy[J]. Journal of Alloys and Compounds,1997,249(1-2):264-267.
APA L. P. Li,Q. A. Wei,Z. J. Kang,M. Q. Rui,&W. H. Su.(1997).The synthesis of La0.875-xEuxNa0.125CrO3 and its study by Eu-151 Mossbauer spectroscopy.Journal of Alloys and Compounds,249(1-2),264-267.
MLA L. P. Li,et al."The synthesis of La0.875-xEuxNa0.125CrO3 and its study by Eu-151 Mossbauer spectroscopy".Journal of Alloys and Compounds 249.1-2(1997):264-267.
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