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Magnetic properties of R2Fe14M3 compounds with M=Ga and Si; R=Y, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm
B. G. Shen; B. Liang; Z. H. Cheng; H. Y. Gong; W. S. Zhan; H. Tang; F. R. deBoer; J. H. J. Buschow
1997
发表期刊Solid State Communications
ISSN0038-1098
卷号103期号:2页码:71-75
摘要Samples with composition R2Fe14M3 (M = Ga and Si; R = Y, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm) have been prepared by are-melting. Crystal-structure studies have shown that the prepared samples are single phase with the rhombohedral Th2Zn17 and/or the hexagonal Th2Ni17 structure. Substitution of Ga for Fe in R2Fe17 leads to an increase of the unit-cell volume, whereas Si substitution reduces the unit-cell volume. The Curie temperatures of the R2Fe14Ga3 and R2Fe14Si3 compounds are much larger than those of the corresponding R2Fe17 compounds. The Fe moment decreases upon Ga or Si substitution. The compounds R2Fe14Ga3 and R2Fe14Si3 With R = Er and Tm exhibit a spin-reorientation transition at low temperature. (C) 1997 Elsevier Science Ltd.
部门归属chinese acad sci,ctr condensed matter phys,beijing 100080,peoples r china. acad sinica,inst met res,shenyang 110015,peoples r china. univ amsterdam,van der waals zeeman inst,nl-1018 xe amsterdam,netherlands.;shen, bg (reprint author), chinese acad sci,inst phys,state key lab magnetism,pob 603,beijing 100080,peoples r china
关键词Neutron-diffraction Solid-solutions Substitution Anisotropy Nd2fe17
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/38070
专题中国科学院金属研究所
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GB/T 7714
B. G. Shen,B. Liang,Z. H. Cheng,et al. Magnetic properties of R2Fe14M3 compounds with M=Ga and Si; R=Y, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm[J]. Solid State Communications,1997,103(2):71-75.
APA B. G. Shen.,B. Liang.,Z. H. Cheng.,H. Y. Gong.,W. S. Zhan.,...&J. H. J. Buschow.(1997).Magnetic properties of R2Fe14M3 compounds with M=Ga and Si; R=Y, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm.Solid State Communications,103(2),71-75.
MLA B. G. Shen,et al."Magnetic properties of R2Fe14M3 compounds with M=Ga and Si; R=Y, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm".Solid State Communications 103.2(1997):71-75.
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