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Local structure of mechanically alloyed nanocrystalline BCC Fe80Cu20 solid solution
Y. Z. Yang; Y. L. Zhu; Q. S. Li; X. M. Ma; Y. D. Dong; G. M. Wang; S. Q. Wei; F. X. Liu; Y. Z. Chuang
1997
发表期刊Physica B-Condensed Matter
ISSN0921-4526
卷号233期号:2-3页码:119-124
摘要The fine structure of mechanically alloyed BCC Fe80Cu20 solid solution has been studied by X-ray diffraction (XRD), Mossbauer spectroscopy and the extended X-ray absorption fine structure (EXAFS) technique. The appearance of Mossbauer spectrum with a broad hyperfine magnetic field distribution demonstrates that the alloying is at an atomic level and complex forms of coordination exist in the solution. EXAFS results further prove the atomic alloying from the clear observation of Cu atoms taking on BCC coordination in the solution. Furthermore, a reduction in the nearest-neighbor coordination number of a center Cu atom but not for a center Fe atom due to surface effect and structure defects indicates the composition nonuniformity that Cu atoms are rich at interface and Fe atoms are slightly rich in the core of a BCC nanocrystal.
部门归属shanghai univ,dept mat sci & engn,shanghai 200072,peoples r china. univ sci & technol china,ctr struct anal,hefei 230026,peoples r china. acad sinica,inst met res,shenyang 110015,peoples r china.;yang, yz (reprint author), guangdong univ technol,dept mat sci & engn,guangzhou 510090,peoples r china
关键词Mechanical Alloying Nanocrystalline Solid Solutions Fine Structure Exafs Fe-cu System Thermal-stability Decomposition Iron
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/38169
专题中国科学院金属研究所
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GB/T 7714
Y. Z. Yang,Y. L. Zhu,Q. S. Li,et al. Local structure of mechanically alloyed nanocrystalline BCC Fe80Cu20 solid solution[J]. Physica B-Condensed Matter,1997,233(2-3):119-124.
APA Y. Z. Yang.,Y. L. Zhu.,Q. S. Li.,X. M. Ma.,Y. D. Dong.,...&Y. Z. Chuang.(1997).Local structure of mechanically alloyed nanocrystalline BCC Fe80Cu20 solid solution.Physica B-Condensed Matter,233(2-3),119-124.
MLA Y. Z. Yang,et al."Local structure of mechanically alloyed nanocrystalline BCC Fe80Cu20 solid solution".Physica B-Condensed Matter 233.2-3(1997):119-124.
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