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Laser-induced coloration of WO3
Y. Zhao; Z. C. Feng; Y. Liang; H. W. Sheng
1997
发表期刊Applied Physics Letters
ISSN0003-6951
卷号71期号:16页码:2227-2229
摘要It has long been recognized that WO3 can be colored through electro-, photo-, and thermo-chromism processes. We report here that WO3 turned to a deep blue color upon just one pulse irradiation of the XeCl excimer laser (lambda = 308 nm, pulse duration = 36 ns, output energy = 100 mJ/pulse). Scanning electron microscopy (SEM) images showed that a melted layer was formed on the surface of the sample. The color change was demonstrated by UV-visible diffuse reflectance. X-ray photoelectron spectroscopy (XPS) showed the partial reduction of WO3 and the appearance of conduction band electrons. Calorimetry measurement results indicated that reoxidation happened at 400-440 degrees C in air. From these experimental results combining with the calculation, it was concluded that the laser-induced coloration is different from ordinary photochromism induced by UV light, and may be attributed to thermochromism. (C) 1997 American Institute of Physics.
部门归属acad sinica,inst met res,natl key lab rsb,shenyang 110015,peoples r china.;zhao, y (reprint author), acad sinica,inst met res,dept microcrystalline & laser proc,shenyang 110015,peoples r china
关键词Amorphous Wo3 Films Photoelectrolysis Electrode Light
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/38222
专题中国科学院金属研究所
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GB/T 7714
Y. Zhao,Z. C. Feng,Y. Liang,et al. Laser-induced coloration of WO3[J]. Applied Physics Letters,1997,71(16):2227-2229.
APA Y. Zhao,Z. C. Feng,Y. Liang,&H. W. Sheng.(1997).Laser-induced coloration of WO3.Applied Physics Letters,71(16),2227-2229.
MLA Y. Zhao,et al."Laser-induced coloration of WO3".Applied Physics Letters 71.16(1997):2227-2229.
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