Laser-induced coloration of WO3 | |
Y. Zhao; Z. C. Feng; Y. Liang; H. W. Sheng | |
1997 | |
发表期刊 | Applied Physics Letters
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ISSN | 0003-6951 |
卷号 | 71期号:16页码:2227-2229 |
摘要 | It has long been recognized that WO3 can be colored through electro-, photo-, and thermo-chromism processes. We report here that WO3 turned to a deep blue color upon just one pulse irradiation of the XeCl excimer laser (lambda = 308 nm, pulse duration = 36 ns, output energy = 100 mJ/pulse). Scanning electron microscopy (SEM) images showed that a melted layer was formed on the surface of the sample. The color change was demonstrated by UV-visible diffuse reflectance. X-ray photoelectron spectroscopy (XPS) showed the partial reduction of WO3 and the appearance of conduction band electrons. Calorimetry measurement results indicated that reoxidation happened at 400-440 degrees C in air. From these experimental results combining with the calculation, it was concluded that the laser-induced coloration is different from ordinary photochromism induced by UV light, and may be attributed to thermochromism. (C) 1997 American Institute of Physics. |
部门归属 | acad sinica,inst met res,natl key lab rsb,shenyang 110015,peoples r china.;zhao, y (reprint author), acad sinica,inst met res,dept microcrystalline & laser proc,shenyang 110015,peoples r china |
关键词 | Amorphous Wo3 Films Photoelectrolysis Electrode Light |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/38222 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. Zhao,Z. C. Feng,Y. Liang,et al. Laser-induced coloration of WO3[J]. Applied Physics Letters,1997,71(16):2227-2229. |
APA | Y. Zhao,Z. C. Feng,Y. Liang,&H. W. Sheng.(1997).Laser-induced coloration of WO3.Applied Physics Letters,71(16),2227-2229. |
MLA | Y. Zhao,et al."Laser-induced coloration of WO3".Applied Physics Letters 71.16(1997):2227-2229. |
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