The Adsoption of Thiourea and its Derivatives on Iron Electrode in Acidic Solution | |
J. H. Dong; G. L. Song; H. C. Lin; C. N. Cao | |
1996 | |
发表期刊 | Acta Physico-Chimica Sinica
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ISSN | 1000-6818 |
卷号 | 12期号:1页码:34-38 |
摘要 | The cathodic adsorption beheaviors of thiourea and 4 of its derivatives on iron in hydrochloric acid and sulphuric acid were investigated by polarizations curves. The accordance of the adsorption beheavior of thiourea on iron in sulphuric acid with Temkin isotherm was deduced from hynamics, and the thiourea took part in the reaction of HER, this phenomena is a negative catalytic effect. The adsorption beheavoris of thiourea and its 4 derivatives and iron in hydrochloric acid was found to be in accord with Langmuir isotherm and this conclusion was deduced from thermodynamics, this phenomena is a blocking effect. |
部门归属 | [dong junhua; song guangling; lin haichao; cao chunan] acad sinica, inst corres & protect met, state key lab corros & protect, shenyang 110015, peoples r china.;dong, jh (reprint author), acad sinica, inst corres & protect met, state key lab corros & protect, shenyang 110015, peoples r china |
关键词 | Thiourea Derivatives Iron Adsorption Cathodic Polarization |
URL | 查看原文 |
WOS记录号 | WOS:000207591300008 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/38270 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. H. Dong,G. L. Song,H. C. Lin,et al. The Adsoption of Thiourea and its Derivatives on Iron Electrode in Acidic Solution[J]. Acta Physico-Chimica Sinica,1996,12(1):34-38. |
APA | J. H. Dong,G. L. Song,H. C. Lin,&C. N. Cao.(1996).The Adsoption of Thiourea and its Derivatives on Iron Electrode in Acidic Solution.Acta Physico-Chimica Sinica,12(1),34-38. |
MLA | J. H. Dong,et al."The Adsoption of Thiourea and its Derivatives on Iron Electrode in Acidic Solution".Acta Physico-Chimica Sinica 12.1(1996):34-38. |
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