Experimental evidence for luminescence from silicon oxide layers in oxidized porous silicon | |
G. G. Qin; H. Z. Song; B. R. Zhang; J. Lin; J. Q. Duan; G. Q. Yao | |
1996 | |
发表期刊 | Physical Review B
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ISSN | 1098-0121 |
卷号 | 54期号:4页码:2548-2555 |
摘要 | A systematic study of the dependence of photoluminescence from porous silicon (PS) on oxidation extent and measurement temperature is given. Oxidation of PS samples at room temperature up to 200 degrees C results in photoluminescence spectra with maxima centered around 1.7 eV. The photoluminescence maxima shift with temperature 10-300 K always toward the 2.7-eV position. These results conflict with predictions of the quantum confinement model for PS luminescence, but can be explained by assuming that several types of luminescence center outside nanoscale Si units in PS are responsible for the luminescence, and that their relative contributions to luminescence change with oxidation extent and measurement temperature. The luminescence centers with luminescence wavelength around 700 nm in SiOx layers, covering the nanoscale silicon particles or on the interfaces of nanoscale Si/SiOx in PS, dominate after sufficient oxidation and their luminescence depends on measurement temperature to a lesser extent than other types of luminescence center do. |
部门归属 | acad sinica,int ctr mat phys,shenyang 110015,peoples r china. beijing univ,dept chem,beijing 100871,peoples r china.;qin, gg (reprint author), beijing univ,dept phys,beijing 100871,peoples r china |
关键词 | Blue-light Emission Visible Luminescence Photoluminescence Si Temperature Evolution Mechanism Oxidation Stability Exciton |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/38379 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. G. Qin,H. Z. Song,B. R. Zhang,et al. Experimental evidence for luminescence from silicon oxide layers in oxidized porous silicon[J]. Physical Review B,1996,54(4):2548-2555. |
APA | G. G. Qin,H. Z. Song,B. R. Zhang,J. Lin,J. Q. Duan,&G. Q. Yao.(1996).Experimental evidence for luminescence from silicon oxide layers in oxidized porous silicon.Physical Review B,54(4),2548-2555. |
MLA | G. G. Qin,et al."Experimental evidence for luminescence from silicon oxide layers in oxidized porous silicon".Physical Review B 54.4(1996):2548-2555. |
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