Thermodynamic investigation on the BaB2O4-BaF2-2NaF-Na2B2O4 reciprocal system | |
W. D. Zhuang; G. H. Rao; J. K. Liang; Y. L. Zhang; Y. Shi; Z. Y. Qiao; J. Y. Shen | |
1996 | |
发表期刊 | Journal of Solid State Chemistry
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ISSN | 0022-4596 |
卷号 | 126期号:1页码:80-87 |
摘要 | The BaB2O4-BaF2-2NaF-NaB2O4 reciprocal system has been investigated by combination of experimental measurements with theoretical calculation. The Na2B2O4-2NaF binary and Na2B2O4-BaF2 pseudo-binary phase diagrams are measured by means of DTA and X-ray diffraction. The thermodynamic functions for all sub-binary systems are derived from measured phase diagrams and thermodynamic data by CAL-PHAD technique, and the sub-binary phase diagrams are calculated according to phase equilibrium principle. Then, the thermodynamic functions for sub-binary systems are extrapolated to the BaB2O4-BaF2-2NaF-Na2B2O4 reciprocal system, and the phase diagram of the reciprocal system is calculated. The calculated phase diagrams are verified by additional experiments. (C) 1996 Academic Press, Inc. |
部门归属 | acad sinica,int ctr mat phys,shenyang 110015,peoples r china. univ sci & technol beijing,dept phys chem,beijing 100083,peoples r china. gen res inst nonferrous met,beijing 100088,peoples r china.;zhuang, wd (reprint author), chinese acad sci,inst phys,pob 603,beijing 100080,peoples r china |
关键词 | Phase-equilibrium Beta-bab2o4 Crystal |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/38520 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. D. Zhuang,G. H. Rao,J. K. Liang,et al. Thermodynamic investigation on the BaB2O4-BaF2-2NaF-Na2B2O4 reciprocal system[J]. Journal of Solid State Chemistry,1996,126(1):80-87. |
APA | W. D. Zhuang.,G. H. Rao.,J. K. Liang.,Y. L. Zhang.,Y. Shi.,...&J. Y. Shen.(1996).Thermodynamic investigation on the BaB2O4-BaF2-2NaF-Na2B2O4 reciprocal system.Journal of Solid State Chemistry,126(1),80-87. |
MLA | W. D. Zhuang,et al."Thermodynamic investigation on the BaB2O4-BaF2-2NaF-Na2B2O4 reciprocal system".Journal of Solid State Chemistry 126.1(1996):80-87. |
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