THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL | |
W. C. Zheng | |
1995 | |
Source Publication | Journal of Physics-Condensed Matter
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ISSN | 0953-8984 |
Volume | 7Issue:23Pages:4499-4505 |
Abstract | In this paper, by introducing a factor f to denote the contraction effect of perovskite crystals along the trigonal axis in the cubic-to-trigonal phase transition, the expressions for calculating the zero-field splitting D, the first excited-state splitting Delta((2)E),and the anisotropy of the EPR g-factor (characterized by Delta g = g(parallel to) - g(perpendicular to)) for 3d(3) ions in the trigonal phase of this pervoskite structure from the rotation angle alpha have been put forward. On the basis of these expressions, the zero-field splitting D, the splitting Delta((2)E) and the anisotropy of the g-factor for Cr3+ in the trigonal phase of a LaAlO3 crystal are calculated by using two parameters obtained from the optical spectra of a similar crystal. The results show reasonable agreement with the experimental values. |
description.department | acad sinica,int ctr mat phys,shenyang 110015,peoples r china.;zheng, wc (reprint author), sichuan univ,dept mat sci,chengdu 610064,peoples r china |
Keyword | Dependence Parameters Ruby Mgo Res |
URL | 查看原文 |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/38773 |
Collection | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | W. C. Zheng. THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL[J]. Journal of Physics-Condensed Matter,1995,7(23):4499-4505. |
APA | W. C. Zheng.(1995).THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL.Journal of Physics-Condensed Matter,7(23),4499-4505. |
MLA | W. C. Zheng."THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL".Journal of Physics-Condensed Matter 7.23(1995):4499-4505. |
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