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THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL
W. C. Zheng
1995
Source PublicationJournal of Physics-Condensed Matter
ISSN0953-8984
Volume7Issue:23Pages:4499-4505
AbstractIn this paper, by introducing a factor f to denote the contraction effect of perovskite crystals along the trigonal axis in the cubic-to-trigonal phase transition, the expressions for calculating the zero-field splitting D, the first excited-state splitting Delta((2)E),and the anisotropy of the EPR g-factor (characterized by Delta g = g(parallel to) - g(perpendicular to)) for 3d(3) ions in the trigonal phase of this pervoskite structure from the rotation angle alpha have been put forward. On the basis of these expressions, the zero-field splitting D, the splitting Delta((2)E) and the anisotropy of the g-factor for Cr3+ in the trigonal phase of a LaAlO3 crystal are calculated by using two parameters obtained from the optical spectra of a similar crystal. The results show reasonable agreement with the experimental values.
description.departmentacad sinica,int ctr mat phys,shenyang 110015,peoples r china.;zheng, wc (reprint author), sichuan univ,dept mat sci,chengdu 610064,peoples r china
KeywordDependence Parameters Ruby Mgo Res
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/38773
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
W. C. Zheng. THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL[J]. Journal of Physics-Condensed Matter,1995,7(23):4499-4505.
APA W. C. Zheng.(1995).THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL.Journal of Physics-Condensed Matter,7(23),4499-4505.
MLA W. C. Zheng."THEORETICAL-STUDIES OF THE ELECTRON-PARAMAGNETIC-RESONANCE AND OPTICAL-SPECTRA OF CR3+ IONS IN THE RHOMBOHEDRAL PHASE OF A LAALO3 CRYSTAL".Journal of Physics-Condensed Matter 7.23(1995):4499-4505.
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