| THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL | |
| Z. Wenchen | |
| 1993 | |
| Source Publication | Journal of Physics and Chemistry of Solids
 |
| ISSN | 0022-3697 |
| Volume | 54Issue:11Pages:1587-1592 |
| Abstract | In order to overcome the difficulties in explaining the zero-field splitting and its stress (along the C3 axis) and hydrostatic pressure dependence for Na2ZnCl4.3H2O:Mn2+ crystal, which arise in previous work, we assume, in this paper, that the Mn2+ ion does not occupy the exact substitutional position of Zn2+ ion in Na2ZnCl4-3H2O, but is displaced about 0.3 angstrom on the C3 axis. Based on this, the zero-field splitting and its stress and pressure dependence have been calculated using the superposition model (and also the spin-orbit coupling mechanism), the results show reasonable agreement with the experimental findings. |
| description.department | acad sinica,int ctr mat phys,shenyang 110015,peoples r china. |
| Keyword | Electron Paramagnetic Resonance Superposition Model Local Lattice Relaxation Mn2++ Ion Na2zncl43h2o S-6-state Ions Parameters Symmetry Spectra Linbo3 Site |
| URL | 查看原文 |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/39149 |
| Collection | 中国科学院金属研究所 |
| Recommended Citation GB/T 7714 | Z. Wenchen. THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL[J]. Journal of Physics and Chemistry of Solids,1993,54(11):1587-1592. |
| APA | Z. Wenchen.(1993).THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL.Journal of Physics and Chemistry of Solids,54(11),1587-1592. |
| MLA | Z. Wenchen."THEORETICAL INVESTIGATIONS OF THE ZERO-FIELD SPLITTING AND ITS STRESS AND PRESSURE-DEPENDENCE FOR MN2+ IN NA2ZNCL43H2O CRYSTAL".Journal of Physics and Chemistry of Solids 54.11(1993):1587-1592. |
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